Mpemba effect: Why hot water can freeze faster than cold

(PhysOrg.com) -- Scientists have known for generations that hot water can sometimes freeze faster than cold, an effect known as the Mpemba effect, but until now have not understood why. Several theories have been proposed, ...

Atomic motion captured in 4-D for the first time

Everyday transitions from one state of matter to another—such as freezing, melting or evaporation—start with a process called "nucleation," in which tiny clusters of atoms or molecules (called "nuclei") begin to coalesce. ...

Graphene 'onion rings' have delicious potential

Concentric hexagons of graphene grown in a furnace at Rice University represent the first time anyone has synthesized graphene nanoribbons on metal from the bottom up—atom by atom.

Revolutionary images of the birth of crystals

At the interface between chemistry and physics, the process of crystallization is omnipresent in nature and industry. It is the basis for the formation of snowflakes but also of certain active ingredients used in pharmacology. ...

Inside the black box of iron oxide formation

From the splendorous red hues in the Grand Canyon to the mundane rust attacking a neglected bicycle, iron hydroxides are all around us. As a matter of fact, they are just as common as quartz, which is the most widely distributed ...

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Nucleation

Nucleation is the extremely localized budding of a distinct thermodynamic phase. Some examples of phases that may form by way of nucleation in liquids are gaseous bubbles, crystals or glassy regions. Creation of liquid droplets in saturated vapor is also characterized by nucleation (see Cloud condensation nuclei). Nucleation of crystalline, amorphous and even vacancy clusters solid materials is also important, for example to the semiconductor industry. Most nucleation processes are physical, rather than chemical, but a few exceptions do exist (e.g. electrochemical nucleation). A good example would be the famous Diet Coke and Mentos eruption. Nucleation normally occurs at nucleation sites on surfaces contacting the liquid or vapor. Suspended particles or minute bubbles also provide nucleation sites. This is called heterogeneous nucleation. Nucleation without preferential nucleation sites is homogeneous nucleation. Homogeneous nucleation occurs spontaneously and randomly, but it requires superheating or supercooling of the medium. Nucleation is involved in such processes as cloud seeding and in instruments such as the bubble chamber and the cloud chamber.

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