Scientists cook up new recipes for taking salt out of seawater

As populations boom and chronic droughts persist, coastal cities like Carlsbad in Southern California have increasingly turned to ocean desalination to supplement a dwindling fresh water supply. Now scientists at the Department ...

Supercapacitors turbocharged by laxatives

An international team of scientists, including a professor of chemistry from the University of Bristol, has worked out a way to improve energy storage devices called supercapacitors, by designing a new class of detergents ...

Watch a tiny space rocket work

Moving a nanosatellite around in space takes only a tiny amount of thrust. Engineers from Michigan Technological University and the University of Maryland teamed up, put a nanoscale rocket under a microscope, and watched ...

Ionic liquids open door to better rare-earth materials processing

U.S. Department of Energy's Ames Laboratory and Critical Materials Institute materials chemist Anja Mudring is harnessing the promising qualities of ionic liquids, salts in a liquid state, to optimize processes for critical ...

One-third of car fuel consumption is due to friction loss

No less than one third of a car's fuel consumption is spent in overcoming friction, and this friction loss has a direct impact on both fuel consumption and emissions. However, new technology can reduce friction by anything ...

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Ionic liquid

Ionic liquids, originally known as liquid electrolytes, ionic melts, ionic fluids, fused salts, liquid salts, or ionic glasses, are liquids comprised predominantly of ions and ion-pairs at some given temperature. Ordinary table salt, or, sodium chloride, consists of sodium cations (Na+) and chloride anions (Cl−) that when heated to several hundred degrees, forms a liquid containing predominantly ions. While many combinations of bulkier and often more asymmetric organic ions also form well defined crystals, with well defined melting points, many instead form glasses prior to thermodynamically stable crystal lattice formation where the cyrstallization kinetics are extremely slow. For example, the salt 1-ethyl-3-methylimidazolium dicyanamide, [C2mim][N(CN)2], melts at Tm = -21 °C, pyridinium chloride, [PyH]Cl, exhibits a melting point of Tm = 144.5 °C but 1-butyl-3,5-dimethylpyridinium bromide, [N-butyl-3,5-dimethyl-Py]Br, exhibits glass formation at Tg = -24 °C.

The term, ionic liquid, includes all classical molten salts, which are comprised of more thermally stable ions, such as sodium with chloride or potassium with nitrate, and has been attested as early as 1943. Recently, it has come to be used for salts whose melting point is below an arbitrary set point of 100 °C. There also exist mixtures of substances which have low melting points, called deep eutectic solvents, or DES, that have many similarities with ionic liquids.

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