Aluminum nanoparticles make tunable green catalysts

Catalysts unlock pathways for chemical reactions to unfold at faster and more efficient rates, and the development of new catalytic technologies is a critical part of the green energy transition.

Scientists reveal how light behaves in formless solids

For a long time, it was thought that amorphous solids do not selectively absorb light because of their disordered atomic structure. However, a new uOttawa study disproves this theory and shows that amorphous solids actually ...

Neutralizing electronic inhomogeneity in cleaved bulk MoS₂

Molybdenum disulfide (MoS2) is a highly versatile material that can function, for example, as a gas sensor or as a photocatalyst in green hydrogen production. Although the understanding of a material usually starts from investigating ...

New migration strategy to boost CO2 reduction to CO

Classical strong metal–support interaction (SMSI) theory describes the way reducible oxide migrates to the surface of metal nanoparticles (NPs) to obtain metal@oxide encapsulation structure during high-temperature H2 thermal ...

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Crystallinity

Crystallinity refers to the degree of structural order in a solid. In a crystal, the atoms or molecules are arranged in a regular, periodic manner. The degree of crystallinity has a big influence on hardness, density, transparency and diffusion. In a gas, the relative positions of the atoms or molecules are completely random. Amorphous materials, such as liquids and glasses, represent an intermediate case, having order over short distances (a few atomic or molecular spacings) but not over longer distances.

Many materials (such as glass-ceramics and some polymers), can be prepared in such a way as to produce a mixture of crystalline and amorphous regions. In such cases, crystallinity is usually specified as a percentage of the volume of the material that is crystalline. Even within materials that are completely crystalline, however, the degree of structural perfection can vary. For instance, most metallic alloys are crystalline, but they usually comprise many independent crystalline regions (grains or crystallites) in various orientations separated by grain boundaries; furthermore, they contain other defects (notably dislocations) that reduce the degree of structural perfection. The most highly perfect crystals are silicon boules produced for semiconductor electronics; these are large single crystals (so they have no grain boundaries), are nearly free of dislocations, and have precisely controlled concentrations of defect atoms.

Crystallinity can be measured using x-ray diffraction, but calorimetric techniques are also commonly used.

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