News tagged with chemical bond
Amazon fungi found that eat polyurethane, even without oxygen
(PhysOrg.com) -- Until now polyurethane has been considered non-biodegradable, but a group of students from Yale University in the US has found fungi that will not only eat and digest it, they will do so even in the absence ...
Making a Point: Picoscale Stability in a Room-Temperature AFM
(PhysOrg.com) -- Forget dancing angels, a research team from the National Institute of Standards and Technology (NIST) and the University of Colorado (CU) has shown how to detect and monitor the tiny amount ...
Mar 25, 2009 |
4.9 / 5 (40) |
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Researchers use super-high pressures to create super battery
The world's biggest Roman candle has got nothing on this. Using super-high pressures similar to those found deep in the Earth or on a giant planet, Washington State University researchers have created a compact, ...
Jul 04, 2010 |
4.2 / 5 (42) |
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New analysis of the structure of spider silks explains paradox of super-strength
Spiders and silkworms are masters of materials science, but scientists are finally catching up. Silks are among the toughest materials known, stronger and less brittle, pound for pound, than steel. Now scientists ...
Nanotechnology / Nanomaterials
Mar 14, 2010 |
5 / 5 (27) |
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'Necropanspermia' suggested as a way of seeding life on Earth
(PhysOrg.com) -- Panspermia is a mechanism for spreading organic material throughout the galaxy, but the destructive effects of cosmic rays and ultraviolet light tend to mean most organisms would be destroyed ...
New way to break some of the strongest chemical bonds
(PhysOrg.com) -- Scientists at Cornell University in the U.S. have found a new way of breaking two of the strongest chemical bonds, at ambient temperature and pressure, and this breakthrough could lead to ...
Discovery of an Unexpected Boost for Solar Water-Splitting Cells
(PhysOrg.com) -- A research team from Northeastern University and the National Institute of Standards and Technology has discovered, serendipitously, that a residue of a process used to build arrays of titania ...
Nanotechnology / Nanomaterials
Apr 22, 2009 |
5 / 5 (22) |
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Inexpensive catalyst that makes hydrogen gas 10 times faster than natural enzyme
Looking to nature for their muse, researchers have used a common protein to guide the design of a material that can make energy-storing hydrogen gas. The synthetic material works 10 times faster than the original ...
Aug 11, 2011 |
4.6 / 5 (20) |
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Novel alloy could produce hydrogen fuel from sunlight
Scientists from the University of Kentucky and the University of Louisville have determined that an inexpensive semiconductor material can be "tweaked" to generate hydrogen from water using sunlight.
Aug 30, 2011 |
4.9 / 5 (15) |
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Water Motions Revealed (w/ Video)
(PhysOrg.com) -- Gaze into a glass of water, and you're unlikely to see much more than your own reflection. But gaze a little deeper using a microscope -- or, better yet, a series of laser pulses and detectors ...
May 21, 2010 |
4.7 / 5 (15) |
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Scientists watch chemical bond break using molecule's electrons
Scientists at the National Research Council of Canada (NRC) and the University of Ottawa (uOttawa) enjoyed a bird's eye view of a chemical bond as it breaks.
Jul 28, 2010 |
4.9 / 5 (14) |
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Scientists Make First Observation of Unique Rydberg Molecule
(PhysOrg.com) -- When Enrico Fermi investigated the Rydberg atom in the '30s, he never imagined that the giant atoms could form molecules. Later, in the '70s and '80s, theoretical physicist Chris Greene predicted ...
Giant virus, tiny protein crystals show X-ray laser's power and potential
Two studies published in the February 3 issue of Nature demonstrate how the unique capabilities of the world's first hard X-ray free-electron laser -- the Linac Coherent Light Source, located at the Depart ...
Feb 02, 2011 |
4.9 / 5 (13) |
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New metal catalyst drives hydrogen fuel reaction forwards and backwards
(PhysOrg.com) -- When it comes to driving hydrogen production, a new catalyst built at Pacific Northwest National Laboratory can do what was previously shown to happen only in nature: store energy in hydrogen and release ...
Feb 16, 2012 |
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Bulky molecules trap boron compounds into a never-before-seen structural arrangement
When it comes to chemical bonding, boron has a reputation for being unconventional. While covalent bonds are usually formed by sharing two electrons between two atoms, some compoundsincluding diboranes ...
Nov 19, 2010 |
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Chemical bond
A chemical bond is the physical process responsible for the attractive interactions between atoms and molecules, and that which confers stability to diatomic and polyatomic chemical compounds. The explanation of the attractive forces is a complex area that is described by the laws of quantum electrodynamics. In practice, however, chemists usually rely on quantum theory or qualitative descriptions that are less rigorous but more easily explained to describe chemical bonding. In general, strong chemical bonding is associated with the sharing or transfer of electrons between the participating atoms. Molecules, crystals, and diatomic gases—indeed most of the physical environment around us—are held together by chemical bonds, which dictate the structure of matter.
Bonds vary widely in their strength which is associated both with the energy required to break them, and the forces they exert on the atoms they hold together. Generally covalent and ionic bonds are often described as "strong", whereas hydrogen bonds and van der Waals' bonds are generally considered to be "weak," although there exist overlaps in strength within these bond classes.
Since opposite charges attract via a basic electromagnetic force, the negatively-charged electrons orbiting the nucleus and the positively-charged protons in the nucleus attract each other. Also, an electron positioned between two nuclei will be attracted to both of them. Thus, the most stable configuration of nuclei and electrons is one in which the electrons spend more time between nuclei, than anywhere else in space. These electrons cause the nuclei to be attracted to each other. However, this assembly cannot collapse to a size dictated by the volumes of these individual particles. Due to the matter wave nature of electrons and their relatively smaller mass, they occupy a very much larger amount of volume compared with the nuclei, and this volume occupied by the electrons keeps the atomic nuclei relatively far apart, as compared with the size of the nuclei themselves.
In the simplest view of a so-called covalent bond, one or more electrons (often a pair of electrons) are drawn into the space between the two atomic nuclei. Here the negatively charged electrons are attracted to the positive charges of both nuclei, instead of just their own. This overcomes the repulsion between the two positively charged nuclei of the two atoms, and so this overwhelming attraction holds the two nuclei in a relatively fixed configuration of equilibrium, even though they will still vibrate at equilibrium position. In summary, covalent bonding involves sharing of electrons in which the positively charged nuclei of two or more atoms simultaneously attract the negatively charged electrons that are being shared. In a polar covalent bond, one or more electrons are unequally shared between two nuclei.
In a simplified view of an ionic bond, the bonding electron is not shared at all, but transferred. In this type of bond, the outer atomic orbital of one atom has a vacancy which allows addition of one or more electrons. These newly added electrons potentially occupy a lower energy-state (effectively closer to more nuclear charge) than they experience in a different atom. Thus, one nucleus offers a more tightly-bound position to an electron than does another nucleus, with the result that one atom may transfer an electron to the other. This transfer causes one atom to assume a net positive charge, and the other to assume a net negative charge. The bond then results from electrostatic attraction between atoms, and the atoms become positive or negatively charged ions.
All bonds can be explained by quantum theory, but, in practice, simplification rules allow chemists to predict the strength, directionality, and polarity of bonds. The octet rule and VSEPR theory are two examples. More sophisticated theories are valence bond theory which includes orbital hybridization and resonance, and the linear combination of atomic orbitals molecular orbital method which includes ligand field theory. Electrostatics are used to describe bond polarities and the effects they have on chemical substances.
For more information about Chemical bond, read the full article at
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