News tagged with chemical bond
Probing hydrogen under extreme conditions
(Phys.org) -- How hydrogen--the most abundant element in the cosmos--responds to extremes of pressure and temperature is one of the major challenges in modern physical science. Moreover, knowledge gleaned ...
Apr 13, 2012 |
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Squeezing polymers produces chemical energy but raises doubts about implant safety
A polymer is a mesh of chains, which slowly break over time due to the pressure from ordinary wear and tear. When a polymer is squeezed, the pressure breaks chemical bonds and produces free radicals: ions with unpaired electrons, ...
Mar 02, 2012 |
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Solved: The mystery of the nanoscale crop circles
(PhysOrg.com) -- Almost three years ago a team of scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) was performing an experiment in which layers of gold mere ...
Mar 02, 2012 |
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New metal catalyst drives hydrogen fuel reaction forwards and backwards
(PhysOrg.com) -- When it comes to driving hydrogen production, a new catalyst built at Pacific Northwest National Laboratory can do what was previously shown to happen only in nature: store energy in hydrogen and release ...
Feb 16, 2012 |
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WSU chemist applies Google software to webs of the molecular world
The technology that Google uses to analyze trillions of Web pages is being brought to bear on the way molecules are shaped and organized.
Feb 13, 2012 |
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Amazon fungi found that eat polyurethane, even without oxygen
(PhysOrg.com) -- Until now polyurethane has been considered non-biodegradable, but a group of students from Yale University in the US has found fungi that will not only eat and digest it, they will do so even in the absence ...
Overcoming cancer drug resistance with nanoparticles
One of the ways in which cancer cells evade anticancer therapy is by producing a protein that pumps drugs out of the cell before these compounds can exert their cell-killing effects. A research team at Northwestern University ...
Nanotechnology / Bio & Medicine
Jan 20, 2012 |
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Comparing energy conversion of plants and solar cells
Scientists now have a way to more accurately compare how efficiently plants and photovoltaic, or solar, cells convert sunlight into energy, thanks to findings by a research consortium that included a U.S. ...
Technology / Energy & Green Tech
Jan 16, 2012 |
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New chemical reaction holds promise for drug development
A team of researchers at the California Institute of Technology (Caltech) has devised a new method for making complex molecules. The reaction they have come up with should enable chemists to synthesize new ...
Jan 12, 2012 |
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Chemists find new way to break amide bonds
(PhysOrg.com) -- Researchers in the University of Bristol's School of Chemistry have found a way to accelerate the breakdown of amide bonds.
Dec 16, 2011 |
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Two-step technique makes graphene suitable for organic chemistry
The future brightened for organic chemistry when researchers at Rice University found a highly controllable way to attach organic molecules to pristine graphene, making the miracle material suitable for a ...
Nanotechnology / Nanomaterials
Nov 29, 2011 |
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New strategy could lead to dose reduction in X-ray imaging
For more than a century, the use of X-rays has been a prime diagnostic tool when it comes to human health. As it turns out, X-rays also are a crucial component for studying and understanding molecules, and a new approach ...
Nov 22, 2011 |
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Bow down to the light: Light-triggered microscale robotic arm makes bending and stretching motions
(PhysOrg.com) -- As miniaturization progresses, microrobots and nanomachines have moved beyond the realm of pure speculation. This technology requires tiny components that can respond to stimulation by undergoing ...
Nov 21, 2011 |
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Scientists carve nanowires out of ultrananocrystalline diamond thin films
A team of scientists working at Argonne National Laboratory's (ANL) Center for Nanoscale Materials has successfully carved ultrananocrystalline diamond (UNCD) thin films into nanowires, boosting the material's functionality ...
Nov 04, 2011 |
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Highly selective catalyst developed for ring-closing olefin metathesis
Research carried out at Boston College, in collaboration with scientists at MIT and the University of Oxford, has led to the development of an efficient and highly selective catalyst for ring-closing olefin metathesis, one ...
Nov 02, 2011 |
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Chemical bond
A chemical bond is the physical process responsible for the attractive interactions between atoms and molecules, and that which confers stability to diatomic and polyatomic chemical compounds. The explanation of the attractive forces is a complex area that is described by the laws of quantum electrodynamics. In practice, however, chemists usually rely on quantum theory or qualitative descriptions that are less rigorous but more easily explained to describe chemical bonding. In general, strong chemical bonding is associated with the sharing or transfer of electrons between the participating atoms. Molecules, crystals, and diatomic gases—indeed most of the physical environment around us—are held together by chemical bonds, which dictate the structure of matter.
Bonds vary widely in their strength which is associated both with the energy required to break them, and the forces they exert on the atoms they hold together. Generally covalent and ionic bonds are often described as "strong", whereas hydrogen bonds and van der Waals' bonds are generally considered to be "weak," although there exist overlaps in strength within these bond classes.
Since opposite charges attract via a basic electromagnetic force, the negatively-charged electrons orbiting the nucleus and the positively-charged protons in the nucleus attract each other. Also, an electron positioned between two nuclei will be attracted to both of them. Thus, the most stable configuration of nuclei and electrons is one in which the electrons spend more time between nuclei, than anywhere else in space. These electrons cause the nuclei to be attracted to each other. However, this assembly cannot collapse to a size dictated by the volumes of these individual particles. Due to the matter wave nature of electrons and their relatively smaller mass, they occupy a very much larger amount of volume compared with the nuclei, and this volume occupied by the electrons keeps the atomic nuclei relatively far apart, as compared with the size of the nuclei themselves.
In the simplest view of a so-called covalent bond, one or more electrons (often a pair of electrons) are drawn into the space between the two atomic nuclei. Here the negatively charged electrons are attracted to the positive charges of both nuclei, instead of just their own. This overcomes the repulsion between the two positively charged nuclei of the two atoms, and so this overwhelming attraction holds the two nuclei in a relatively fixed configuration of equilibrium, even though they will still vibrate at equilibrium position. In summary, covalent bonding involves sharing of electrons in which the positively charged nuclei of two or more atoms simultaneously attract the negatively charged electrons that are being shared. In a polar covalent bond, one or more electrons are unequally shared between two nuclei.
In a simplified view of an ionic bond, the bonding electron is not shared at all, but transferred. In this type of bond, the outer atomic orbital of one atom has a vacancy which allows addition of one or more electrons. These newly added electrons potentially occupy a lower energy-state (effectively closer to more nuclear charge) than they experience in a different atom. Thus, one nucleus offers a more tightly-bound position to an electron than does another nucleus, with the result that one atom may transfer an electron to the other. This transfer causes one atom to assume a net positive charge, and the other to assume a net negative charge. The bond then results from electrostatic attraction between atoms, and the atoms become positive or negatively charged ions.
All bonds can be explained by quantum theory, but, in practice, simplification rules allow chemists to predict the strength, directionality, and polarity of bonds. The octet rule and VSEPR theory are two examples. More sophisticated theories are valence bond theory which includes orbital hybridization and resonance, and the linear combination of atomic orbitals molecular orbital method which includes ligand field theory. Electrostatics are used to describe bond polarities and the effects they have on chemical substances.
For more information about Chemical bond, read the full article at
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