Metal nanoparticles shine with customizable color (w/ video)

February 23rd, 2012 in Nanotechnology / Nanophysics
The color output of a new type of optical filter created at Harvard depends on the polarization of the incoming light. Credit: Image courtesy of Tal Ellenbogen.


The color output of a new type of optical filter created at Harvard depends on the polarization of the incoming light. Credit: Image courtesy of Tal Ellenbogen.

(PhysOrg.com) -- Engineers at Harvard have demonstrated a new kind of tunable color filter that uses optical nanoantennas to obtain precise control of color output.

Whereas a conventional can only produce one fixed , a single active filter under exposure to different types of light can produce a range of colors.

The advance has the potential for application in televisions and , and could even be used to create invisible security tags to mark . The findings appear in the February issue of .

Kenneth Crozier, Associate Professor of at the Harvard School of Engineering and Applied Sciences (SEAS), and colleagues have engineered the size and shape of metal nanoparticles so that the color they appear strongly depends on the of the light illuminating them. The nanoparticles can be regarded as antennas—similar to antennas used for wireless communications—but much smaller in scale and operating at visible frequencies.

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The optical nanoantenna technology can create a pixel with a uniform color or complex patterns with colors varying as a function of position.

"With the advances in nanotechnology, we can precisely control the shape of the optical nanoantennas, so we can tune them to react differently with light of different colors and different polarizations," said co-author Tal Ellenbogen, a postdoctoral fellow at SEAS. "By doing so, we designed a new sort of controllable color filter."

Conventional RGB filters used to create color in today's televisions and monitors have one fixed output color (red, green, or blue) and create a broader palette of hues through blending. By contrast, each pixel of the nanoantenna-based filters is dynamic and able to produce different colors when the polarization is changed.

To demonstrate their work, researchers at Harvard created a plate of chromatic plasmonic polarizers that spells out the acronym "LSP." Under light of different polarizations, the letters and the background change color. The image at far right shows the antennas themselves, as viewed through a scanning electron microscope. Credit: Photos courtesy of Tal Ellenbogen.

The researchers dubbed these filters "chromatic plasmonic polarizers" as they can create a pixel with a uniform color or complex patterns with colors varying as a function of position.

To demonstrate the technology's capabilities, the acronym LSP (short for localized surface plasmon) was created. With unpolarized light or with light which is polarized at 45 degrees, the letters are invisible (gray on gray). In polarized light at 90 degrees, the letters appear vibrant yellow with a blue background, and at 0 degrees the color scheme is reversed. By rotating the polarization of the incident light, the letters then change color, moving from yellow to blue.

"What is somewhat unusual about this work is that we have a color filter with a response that depends on polarization," says Crozier.

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The acronym LSP, short for localized surface plasmon, is displayed. With unpolarized light or with light which is polarized at 45 degrees the letters are invisible (gray on gray). In polarized light at 90 degrees the letters appear vibrant yellow with a blue background and at 0 degrees the color scheme is reversed. By rotating the polarization of the incident light the letters then change color, moving from yellow to blue.

The researchers envision several kinds of applications: using the color functionality to present different colors in a display or camera, showing polarization effects in tissue for biomedical imaging, and integrating the technology into labels or paper to generate security tags that could mark money and other objects.

Seeing the color effects from current fabricated samples requires magnification, but large-scale nanoprinting techniques could be used to generate samples big enough to be seen with the naked eye. To build a television, for example, using the nanoantennas would require a great deal of advanced engineering, but Crozier and Ellenbogen say it is absolutely feasible.

Crozier credits the latest advance, in part, to taking a biological approach to the problem of color generation. Ellenbogen, who is, ironically, colorblind, had previously studied computational models of the visual cortex and brought such knowledge to the lab.

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Each pixel of the nanoantenna-based filters is dynamic and able to produce different colors when the polarization is changed.

"The chromatic plasmonic polarizers combine two structures, each with a different spectral response, and the human eye can see the mixing of these two spectral responses as color," said Crozier.

"We would normally ask what is the response in terms of the spectrum, rather than what is the response in terms of the eye," added Ellenbogen.

Provided by Harvard University

"Metal nanoparticles shine with customizable color (w/ video)." February 23rd, 2012. http://phys.org/news/2012-02-metal-nanoparticles-customizable.html