The sweetness of biodegradable plasticsDecember 14, 2010 in Chemistry / Materials Science
Environmentalists around the world agree ― plastic bags are choking our landfills and polluting our seas. Now a Tel Aviv University researcher is developing new laboratory methods using corn starch and sugar to help sustainable plastics -- those that biodegrade and are even tougher than those made from petrochemicals -- compete in the industry.
The answer to the problem, Prof. Moshe Kol of Tel Aviv University's School of Chemistry says, is a new variety of catalysts ― substances that initiate or sustain chemical reactions in other substances. His team has already developed several of these new catalysts, and it's currently expanding its activities in partnership with the University of Aachen in Germany and the University of Bath in England.
Prof. Kol is improving the process of making these "green" plastics stronger and more heat-resistant, allowing them to be used in a variety of ways, from the automotive industry to Starbucks coffee cups. The type of plastic the partners are working on, polylactic acid or PLA, is a kind of biodegradable plastic made from renewable plant sources such as corn, wheat or sugarcane. It's already used in bottles, bags, and film, and like polyester can even be woven into clothes.
Making stronger and biodegradable "Lego blocks"
The new catalysts enable the polymerization of lactide, which is the building block of a corn-based plastic. Conventional catalysts have limited control of the way in which these building blocks ― the corn-based molecules ― are assembled ― and they may be toxic. But Prof. Kol's catalysts can be used more safely and efficiently, making "green" plastics more commercially feasible.
"The structure of these corn-based plastics depends on several parameters. The most important is the character of the building blocks, like Lego blocks, that hold the material together," says Prof. Kol. He aims to make sustainable corn-based plastics complement or replace the petroleum-based plastics which can take a millenium to degrade, leaving harmful pollutants in the soil and in water. Corn-based plastic wouldn't cause any adverse health effects and would be expected to biodegrade in a compost bin in a matter of months.
Lord of the plastic ring
Plastics won't be going away any time soon, Prof. Kol suggests, pointing to the movement from concrete or stainless steel to plastic in a variety of industries. Replacing the steel manifold of a car with a plastic substitute would cut down on fuel consumption, and replacing a water pipe made of concrete or metal with one made of corrosion- and crack-resistant plastic may improve the quality of our drinking water.
For disposable items, a perfect plastic material would be a polymer made from renewable resources, that degrades to its original non-toxic form. Plastics made from corn sugar are the most desirable in the industry at the moment.
The preliminary results of Prof. Kol's efforts are in, and the plastics that he and his team produce in the lab look and feel like polystyrene, which could be used for making drinking cups, for example. Rigid and transparent, the drinking cups currently only work for liquids under 122 degrees Fahrenheit, but they represent a first big step into greening plastics and the chemical industry.
Provided by Tel Aviv University
"The sweetness of biodegradable plastics" December 14, 2010 http://phys.org/news/2010-12-sweetness-biodegradable-plastics.html