Physicists create carbon magnetism by removing atoms from graphite

Mar 22, 2010 By Lisa Zyga feature
This 3D image, obtained with a scanning tunneling microscope, shows a single isolated atomic vacancy. The scientists identified the presence of a sharp resonance peak on top of individual vacancies, which can be associated with a magnetic moment. Image credit: M. M. Ugeda, et al. ©2010 APS.

( -- Physicists have found that, by removing individual atoms from a graphite surface, they can create local magnetic moments in the graphite. The discovery could lead to techniques to artificially create magnets that are nonmetallic and biocompatible, as well as cheaper and lighter than current magnets.

The scientists, Miguel Ugeda, Ivan Brihuega, and José Gómez-Rodríguez, all from the Autonomous University of Madrid, along with Francisco Guinea from the Institute of Materials Science of Madrid, have published the results of their study in a recent issue of .

“It is a pressing challenge of nanotechnology to be able to integrate graphene in real electronic devices,” Brihuega told “To this end, it is mandatory to understand how the presence of single atomic defects modifies its properties. In our work, we use a scanning tunneling microscope in ultra-clean environments to address such a fundamental question for a graphene-like system, a graphite surface. Our main result is our capability to examine at the atomic scale the intrinsic impact that each single atom removed from the surface has in the electronic and magnetic properties of the system.”

As the scientists explain, creating atomic vacancies in graphene-like materials by removing has a strong impact on the mechanical, electronic, and magnetic properties of the materials. In previous studies, researchers have investigated the effects of atomic vacancies on the properties of the material as a whole. In the current study, the scientists wanted to probe deeper and see what happens at each individual vacancy.

In their experiments, the physicists used highly ordered pyrolytic graphite, which consists of stacked graphene sheets that follow the AB-AB stacking sequence. This means that one graphene sheet (B) is slightly shifted with respect to the upper layer (A) in such a way that half of the carbon atoms of the upper sheet A have a carbon atom located exactly below them, while the other half do not.

First, the researchers peeled off some upper graphene sheets in ultra-clean environments in order to ensure that the top graphene sheet, i.e. the graphite surface, was completely free of impurities. Then they created single vacancies by applying low-energy ion irradiation, using just enough energy to displace the surface atoms and produce atomic point defects.

Using a homemade low-temperature scanning tunneling microscope, the scientists could identify the presence of a sharp resonance peak on top of individual vacancies. The resonance peaked around the Fermi level, which has been predicted in many theoretical studies but has never been experimentally observed before now.

As the scientists explain, the resonance at a vacancy can be associated with a magnetic moment. The vacancies cause nearby electron spins to align due to repulsive electron-electron interactions, which leads to the formation of the magnetic moments. In addition, vacancies at different sites induce different kinds of magnetic moments, which can interact with each other. This interaction points to the possibility of inducing a macroscopic ferromagnetic state in the entire graphite material simply by removing random individual carbon atoms.

“In a pristine carbon system, one would never expect to find magnetism because of the tendency of its electrons to couple in pairs by forming covalent bonds,” Brihuega explained. “The association of electrons in pairs runs against the existence of a net moment, since the total spin of the electronic bond will be zero. By removing one carbon atom from the surface, what we do precisely is to break these covalent bonds and as a result we create a localized state with a single unpaired electron that will generate a .”

Overall, the results not only confirm the accuracy of theoretical models, but also have further implications. For example, the observed resonances may enhance graphene’s chemical reactivity. In terms of applications, the results could lead to innovative magnets.

“To create a magnet from a pure carbon system is a tantalizing possibility since this would be a metal-free magnet and thus optimal for applications in biomedicine,” Brihuega said. “In addition, it should be much cheaper to produce than conventional magnets since, to give some numbers, a ton of carbon costs around a thousand times less than a ton of nickel ($16 vs. $16,000), a commonly used material in actual magnets. In the case of graphene systems, one would also have flexibility and lightness as additional advantages; but to date, the total magnetization reported for these systems is very low when compared with the strongest existing magnets.

“In my opinion,” he added, “the brightest future in terms of applications stems in the emerging field of spintronics, i.e. in trying to exploit the 'spin' of the unpaired electron for creating new spin-based devices.”

Explore further: Pinpoint laser heating creates a maelstrom of magnetic nanotextures

More information: M. M. Ugeda, I. Brihuega, F. Guinea, and J. M. Gómez-Rodríguez. “Missing Atom as a Source of Carbon Magnetism.” Physical Review Letters 104, 096804 (2010). DOI:10.1103/PhysRevLett.104.096804

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3 / 5 (2) Mar 22, 2010
..vacancies at different sites induce different kinds of magnetic moments, which can interact with each other. This interaction points to the possibility of inducing a macroscopic ferromagnetic state in the entire graphite material simply by removing random individual carbon atoms
This could also lead to novel methods for the creation of entirely new carbon nano structures, such as geodesic buckey domes, thorugh the attractive properties of quantitatively balanced, as opposed to random, isolated assymmetries in the graphene sheet.
5 / 5 (2) Mar 22, 2010
a ton of carbon costs around a thousand times less than a ton of nickel ($16 vs. $16,000),

Ah, well....a ton of carbon isn't a ton of graphene. Processing cost for making a ton of graphene is still substantially higher than $16,000 (and likely to remain so for a while).

Would be interesting to know how strong these carbon-magnets are compared to other types of magnets by volume (or weight).

It seems that the only thing graphene can't do (yet) is clean the coffee pot. Fascinating stuff.

Also different stacking sequences should be tried. Magnetism is either a product of circular electron movements or of inhomogeneous electron spin alignment. With the proper geometry these effects may become more pronounced.
1 / 5 (2) Mar 22, 2010
Sometimes I think carbon nanomaterials are going to do everything in the future; they will be able to make solar cells, ultracapacitors, batteries, artificial muscles and motors, thermoelectric generators, gene therapy delivery vehicles, computer chips, neural interfaces to hook them up to thew brain and peripheral nerves, LEDs
replacements for bones, artificial retinas etc etc.
Everything will be made of carbon nanotubes and graphene!
not rated yet Mar 23, 2010
Before they report this flux discovery, hopefully they were in a Faraday chamber when they said they discovered it. This way they didnt read some transient WIFI..... :-D
3.7 / 5 (3) Mar 23, 2010
It seems that the only thing graphene can't do (yet) is clean the coffee pot.
Why in the world would you want to clean the coffee pot? Don't you know that better tasting coffee, and better tasting tea, too, is poured from well used coffee and teapots?
not rated yet Mar 24, 2010
Lasers are used extensively in eye surgery to remove unwanted material from the eye or reshape the eye lens. These lasers use pulses of very intense radiation to literally blast away material.
not rated yet Mar 29, 2010
its amazing what scientists are achieving in our generation.
not rated yet Apr 02, 2010
There was one good question: how strong are these
"carbon magnets"? The problem is that these carbon "ferromagnetics" REPULSE from magnets. Because very small traces of ferromagnetism are much weaker than traditional and well known strong diamagnetism of graphite. Graphen is also diamagnetic. How strong? As strong as 20 ppm of Fe an dthat is typical concentration of impurity in commercial graphite of even very good quality
not rated yet Apr 02, 2010
So far authors showed that if they create dangling bond-it has unpaired spin, oh really?? It is nic epicture but result is completely trivial and has nothing to do with magnets, amorphou silicon has lot of free spins and no ferromagnetism. Magnetic moments must align to make a magnet, that i snot yet shown for carbon.

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