Sounding out Congo Red

May 06, 2008

Brightly colored dyes such as the shimmering Congo Red commonly used in silk clothing manufacture are notoriously difficult to dispose of in an environmentally benign way.

Congo Red is an azo dye, it is toxic to many organisms and is a suspected carcinogen and mutagen. To give it its full name it is the disodium salt of 3,3'-(1E,1'E)-biphenyl-4,4'-diylbis(diazene-2,1-diyl)bis(4-aminonaphthalene-1-sulfonate). It is a benzidine-based anionic disazo dye. Benzidine and Congo Red are, however, banned in many countries because of health concerns. But, it is still widely used in several countries.

Apparently it is used not only to dye silk a gorgeous red, but cleverly adds a second shimmering color and rending the red silk shot through with yellow. It also represents a significant effluent problem along with related dyes from textiles, printing and dyeing, paper, rubber, and plastic industries. Its structural stability makes it highly resistant to biodegradation, and obviously its bright color and toxicity are entirely undesirable in the environment.

Writing in the International Journal of Environment and Waste Management (2008, 2, 309-319), Srinivas Sistla and Suresh Chintalapati, from Hyderabad, India, explain a new approach to degrading Congo Red based on ultrasound.

The researchers point out that advanced oxidation processes (AOP) are currently being developed for remediation of contaminated effluent because they generate no hazardous sludge. Oxidative degradation is based on free radical attack using powerful oxidants.

However, Sistla and Chintalapati suggest that sonolysis, break down of an organic compound with ultrasound, has so far been investigated only rarely as an alternative remediation technology. Under well-established 'extreme' conditions, materials irradiated with sound at frequencies around 50 kHz are essentially ripped apart by the formation of free radicals, say the researchers. Carbon dioxide and water are the usual products, although with the case of azo dyes, nitrogen would also feature in the byproducts.

Sonication of Congo Red in the aqueous phase with 50 kHz ultrasound transforms it into a milieu of less toxic intermediates that can then be broken down still further by conventional industrial waste water biodegradation treatment. As a proof of principle, the researchers suggest that the combination of ultrasound and biodegradation could allow the color to be removed from dye-contaminated industrial effluent effectively and the toxicity reduced to negligible levels. "The results obtained from this study revealed the ability of ultrasonic irradiation to transform the aromatic inhibitory compounds to less toxic intermediates, which can be further utilized in aerobic/anaerobic oxidation," the researchers conclude.

Source: Inderscience Publishers

Explore further: Indians rally against climate change ahead of UN talks

add to favorites email to friend print save as pdf

Related Stories

Thermal monitoring of volcanic activity from space

Jun 06, 2014

Data from the Meteosat satellite 36,000 km from Earth, has been used to measure the temperature of lava at the Nyiragongo lava lake in the Democratic Republic of Congo. An international team compared data ...

Where the wild things go... when there's nowhere else

Feb 28, 2013

Ecologists have evidence that some endangered primates and large cats faced with relentless human encroachment will seek sanctuary in the sultry thickets of mangrove and peat swamp forests. These harsh coastal ...

Birds may spread, not halt, fever-bearing ticks

Nov 30, 2012

Turkey raises and releases thousands of non-native guineafowl to eat ticks that carry the deadly Crimean-Congo hemorrhagic fever virus. Yet research suggests guineafowl eat few ticks, but carry the parasites ...

Recommended for you

Green dream: Can UN summit revive climate issue?

18 hours ago

Five years ago, the environment movement was in its heyday as politicians, actors, rock stars and protestors demanded a looming UN summit brake the juggernaut of climate change.

Rio's Olympic golf course in legal bunker

Sep 18, 2014

The return of golf to the Olympics after what will be 112 years by the time Rio hosts South America's first Games in 2016 comes amid accusations environmental laws were got round to build the facility in ...

User comments : 0