Ultrafast electron microscopy reveals switchable nanochannels in materials

Mar 05, 2008

Microscopic fissures in a tiny crystal open and close—on command. Researchers led by Ahmed H. Zewail successfully used ultrafast electron microscopy (UEM) to observe nanoscopic structures at their “exercises”, as they report in the journal Angewandte Chemie. Such switchable nanochannels could be useful for future nanoelectronics and nanoscopic “machines”.

Zewail and his team at the California Institute of Technology (Pasadena, USA) are renowned for their work in ultrafast science and technology. Zewail received the Nobel Prize in Chemistry in 1999 for the development of ultrafast laser techniques that are capable of revealing the motions of individual atoms within a molecule during a reaction.

The most recent development to spring from Zewail’s Laboratory is ultrafast electron microscopy. This technique is a combination of a femtosecond optical system (a femtosecond equals 10-15 seconds) with a high-resolution electron microscope; the result is a new tool with extremely high resolution in time as well as in space.

Zewail and his team have now discovered that needle-shaped microcrystals of copper and the organic compound TCNQ (7,7,8,8-tetracyanoquinodimethane, C12H4N4 ), a crystalline, quasi-one-dimensional semiconductor, exhibit optomechanical phenomena that could be of use in nanoelectronic applications.

The investigation showed that these crystals stretch out to become longer (but not wider) when they are irradiated with laser pulses in the microscope. If the irradiation is switched off, they contract back to their original size. This effect was most obvious when one of these needles was broken by the shock of a short, strong laser pulse: A small crack of some ten to one hundred nanometers forms at the break. When the crystal is stretched out under irradiation, the nanoscale channel closes up; upon contraction, it reappears. The phenomenon is reversible, as confirmed by UEM.

Why do these micromaterials stretch under light? Within the crystal, the negatively charged TCNQ ions are arranged so that their central, flat, six-membered rings are piled up on top of each other in the long direction of the needle. The energy of a laser pulse excites electrons; part of this energy is transferred, resulting in uncharged TCNQ molecules. For the uncharged TCNQ, the stacked arrangement is no longer favorable, they now require more space and cause the crystal to grow longer. The degree of stretching depends on the strength of the energy absorbed.

“Our fundamental in situ UEM observations, which reveal the behavior of nanoscopic matter in space and time, opens up new areas to explore, especially in materials science, nanotechnology, and biology,” says Zewail.

Citation: Ahmed H. Zewail, Controlled Nanoscale Mechanical Phenomena Discovered with Ultrafast Electron Microscopy, Angewandte Chemie International Edition 2007, 46, No. 48, 9206–9210, doi: 10.1002/anie.200704147

Source: Wiley

Explore further: Study reveals new characteristics of complex oxide surfaces

add to favorites email to friend print save as pdf

Related Stories

Watching nanoscale fluids flow

Jun 27, 2014

(Phys.org) —At the nanoscale, where objects are measured in billionths of meters and events transpire in trillionths of seconds, things do not always behave as our experiences with the macro-world might ...

Moving microscopic vision into another new dimension

Jun 29, 2011

Scientists who pioneered a revolutionary 3-D microscope technique are now describing an extension of that technology into a new dimension that promises sweeping applications in medicine, biological research, ...

Caltech scientists film photons with electrons

Dec 16, 2009

(PhysOrg.com) -- Techniques recently invented by researchers at the California Institute of Technology -- which allow the real-time, real-space visualization of fleeting changes in the structure of nanoscale ...

Recommended for you

A crystal wedding in the nanocosmos

Jul 23, 2014

Researchers at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), the Vienna University of Technology and the Maria Curie-Skłodowska University Lublin have succeeded in embedding nearly perfect semiconductor ...

PPPL studies plasma's role in synthesizing nanoparticles

Jul 22, 2014

DOE's Princeton Plasma Physics Laboratory (PPPL) has received some $4.3 million of DOE Office of Science funding, over three years, to develop an increased understanding of the role of plasma in the synthesis ...

User comments : 0