Measurement and data analysis techniques developed at the Department of Energy's Oak Ridge National Laboratory could provide new insight into performance-robbing flaws in crystalline structures, ultimately improving the performance of solar cells.
While solar cells made from light-harvesting perovskite (an organic-inorganic hybrid) materials have recently eclipsed the 20 percent efficiency mark, researchers believe they could do better if they had a clearer picture of energy flow at the nanometer scale. The ORNL discovery, described in a paper published in ACS Photonics, synchronizes microscopy, ultra-short pulses of laser light and data analytics to extract images with single-pixel precision, providing unprecedented detail.
"If we can see exactly and in real time what is happening, we can map out the electronic processes in space instead of relying on snapshots gleaned from spatial averages," said Benjamin Doughty, one of the authors and a member of ORNL's Chemical Sciences Division.
Armed with information about what electrons are doing inside the material, researchers believe they can make improvements that lead to solar cells that are more efficient and potentially less expensive.
"With conventional approaches of studying photovoltaic materials, we are unable to accurately map out electronic processes and how electrons are getting lost," Doughty said. "Those processes can translate into losses in efficiency."
The experiment consists of optically pumping the thin film sample with a 50 femtosecond—or 50 millionths of a billionth of a second—laser pulse and then measuring changes in light absorption with a second laser pulse in the material. The technique, called femtosecond transient absorption microscopy, consists of a tabletop of lasers, optics and a microscope. The net result is a pixel-by-pixel map of the material being studied and information researchers can use to improve performance.
"The ability to identify what will be created after the solar cell absorbs a photon, either a pair of free charges or their bound form called an exciton, is crucial from both fundamental and applied perspectives," said co-author Yingzhong Ma, who led the research team. "We found that both free charges and excitons are present, and the strength of our approach lies in not only identifying where they are but also determining what their relative contributions are when they are both present at a given spatial location."
A key remaining challenge is to understand what causes the observed spatial difference, said Ma, so he and colleagues are exploring an all-optical imaging approach that would allow them to correlate electronic dynamics with underlying structural information. This approach may also help researchers map and understand perovskite degradation issues associated with moisture. Ma noted that this must be resolved before solar cells based on this class of materials can be successful.
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Mary Jane Simpson et al. Separation of Distinct Photoexcitation Species in Femtosecond Transient Absorption Microscopy, ACS Photonics (2016). DOI: 10.1021/acsphotonics.5b00638