Direct reaction heavy atoms to catalyst surface demonstrated

Jul 29, 2014
Ruthenium crystal covered with oxygen atoms in the experimental set-up Harpoen. Credit: Fundamental Research on Matter (FOM)

Researchers from FOM Institute DIFFER are the first to have demonstrated that heavier atoms in a material surface can react directly with a surrounding gas. The so-called Eley-Rideal reaction has never previously been demonstrated for atoms heavier than hydrogen. The Eley-Rideal process requires less energy than a reaction between two atoms that are both attached to the material. The discovery could lead to more efficient catalysts for the production of synthetic fuel, for example. The researchers published the results on 29 July online in Physical Review Letters.

Most chemical reactions on a material surface (catalyst) follow the Langmuir-Hinshelwood scheme: from the surroundings adhere to the material and move randomly across the surface until they meet each other. At that spot the atoms react with each other and are subsequently released from the surface. In Eley-Rideal reactions a particle on the surface instead reacts directly with an atom from the surroundings that is rapidly moving past it. According to the theory, this type of reaction takes place most easily with light, rapidly moving atoms. In practice, the Eley-Rideal reaction has only been demonstrated with the lightest atom, hydrogen. The team from DIFFER, the Materials innovation institute M2i and the Van 't Hoff Institute for Molecular Sciences in Amsterdam have now demonstrated for the first time that heavier atoms such as nitrogen and oxygen can also undergo an Eley-Rideal reaction.

The direct Eley-Rideal reaction between the surrounding gas and an atom that is attached to the surface had never previously been observed for heavier atoms. Credit: Fundamental Research on Matter (FOM)

Rebound

"In our set-up, Harpoen, we can directly observe the difference between the two types of reaction", explains research leader Dr Teodor Zaharia. His team covered a surface of ruthenium with a layer of and fired a focused beam of at this to obtain the reaction product nitrogen oxide. "The Eley-Rideal reaction takes place within a fraction of a second: the original kinetic energy of the nitrogen is conserved and you can therefore observe the reaction product rebounding from the surface at the same angle as which the original nitrogen atom collided with it." In the Langmuir-Hinshelwood reaction, however, there is no link between the direction of movement of the original atoms and the reaction products; due to the random walk across the surface the information about the original direction of movement is lost. Using detectors that can measure the direction of the reaction product, Zaharia and his team could unequivocally observe the fingerprint of the Eley-Rideal reaction.

The higher energy of the reaction products also revealed that an Eley-Rideal reaction had taken place: just one of the reacting atoms needs to break its attachment to the surface as a result of which less energy is needed. The Eley-Rideal reaction between heavier atoms is therefore attractive for applications in catalysis. The offers extra control over which particles react and that could lead to new ways of producing and processing materials. The research will be continued in a collaboration between DIFFER and the Center of Interface Dynamic for Sustainability that fellow researcher and former director of DIFFER Aart Kleyn has set up in the Chinese city of Chengdu.

Explore further: Scientists discover channel used by catalyst to produce ammonia, vital for food and fuel crops

More information: 'Eley-Rideal reactions with N atoms at Ru(0001): Formation of NO and N2T. Zaharia, A. Kleijn, M. Gleeson, Physical Review Letters, 21 July 2014.

add to favorites email to friend print save as pdf

Related Stories

Improving the cost and efficiency of renewable energy storage

Jul 17, 2014

A major challenge in renewable energy is storage. A common approach is a reaction that splits water into oxygen and hydrogen, and uses the hydrogen as a fuel to store energy. The efficiency of 'water splitting' depends heavily ...

Process holds promise for production of synthetic gasoline

Dec 02, 2013

A chemical system developed by researchers at the University of Illinois at Chicago can efficiently perform the first step in the process of creating syngas, gasoline and other energy-rich products out of carbon dioxide.

Recommended for you

Smartgels are thicker than water

Sep 19, 2014

Transforming substances from liquids into gels plays an important role across many industries, including cosmetics, medicine, and energy. But the transformation process, called gelation, where manufacturers ...

Separation of para and ortho water

Sep 18, 2014

(Phys.org) —Not all water is equal—at least not at the molecular level. There are two versions of the water molecule, para and ortho water, in which the spin states of the hydrogen nuclei are different. ...

User comments : 0