Atomic mechanism for historic materials transformation

May 2, 2014 by Mike Ross
This graphic depicts the transformation of cadmium sulfide nanocrystals from a hexagonal arrangement (left) to a cubic one (right). A slightly compressed intermediate state that SLAC-led researchers saw is portrayed in the middle. Credit: Greg Stewart/SLAC

( —SLAC-led researchers have made the first direct measurements of a small and extremely rapid atomic rearrangement, associated with a class called martensitic transformations, that dramatically changes the properties of many important materials, such as doubling the hardness of steel and causing shape-memory alloys to revert to a previous shape.

Using high-pressure shock waves and ultrashort X-ray pulses at the Linac Coherent Light Source (LCLS), the researchers observed the details of how this transformation changed the internal atomic structure of a model system, perfect of cadmium sulfide. In the process, they saw for the first time that the nanocrystals pass through a theoretically-predicted intermediate state when undergoing this change.

"To design and engineer new materials with desired properties, we would like to understand the detailed microscopic pathways they follow as they transform," said the team's leader, Aaron Lindenberg, an assistant professor at SLAC and Stanford. "The martensitic transformation is especially important since it occurs in so many important materials. Our technique should ultimately help us see what's happening in other atomic transformations as well."

The team's research results were published last month in Nano Letters.

A composite of about 300 stop-action X-ray diffraction images shows the martensitic transformation of cadmium sulfide nanocrystals. Looking from left to right, the light blue line at the top comes from the hexagonal atomic arrangement. It disappears about 250 picoseconds (trillionths of a second) after the beginning of the experiment and is replaced about 50 picoseconds later (to the right) by the signature of the cubic form: a bright blue line above the dark red line on the right side of the image. Credit: Joshua Wittenberg/SLAC and Stanford

Named after pioneering German metallurgist Adolf Martens, the martensitic transformation involves collective short-range movements of the atoms in a crystalline solid as it responds to stress. It has been studied for more than 100 years after Martens and colleagues identified that an altered crystalline form in rapidly cooled high-carbon steel was responsible for its enhanced hardness. While the actual atomic movements in martensitic transformations are typically smaller than a nanometer, they can have huge effects on a material's properties. In addition to hardening steel and facilitating , the martensitic transformation underlies such diverse phenomena as geological deformation due to plate tectonics and the mechanism by which invading viruses puncture the walls of cells.

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A video made from about 300 stop-action X-ray diffraction images shows details of the martensitic transformation of cadmium sulfide nanocrystals. The appearance of a bright blue circle in the gap between the two red-highlighted circles is the signature of the transformation's cubic-form endpoint. Credit: Joshua Wittenberg/SLAC and Stanford

They hit a metal foil with an intense infrared laser pulse, causing it to explode and send a high-pressure shock crashing through the nanocrystals. Pressure from the passing shock wave initiated the transformation. The LCLS X-ray pulses were timed to hit the sample at various split-second times after the shock, producing stop-action X-ray diffraction images that showed the precise positions of the nanocrystal's atoms during various stages of the transformation, which took only 50 trillionths of a second to complete. The scientists also varied the laser intensity to create shocks of different peak pressures.

The team found that the transformations caused by the higher-pressure shocks proceeded directly from hexagonal to cubic, while those triggered by the lower-pressure shocks formed a temporary intermediate state. Calculated simulations by other researchers had predicted the intermediate, Lindenberg said. But its absence in the high-pressure case may be an indication that strong shocks act like catalysts, lowering the energy barrier of the transformation so it can proceed directly.

"This set of experiments shows the power of using LCLS, high-power lasers and nanocrystals to examine the rapid atomic rearrangements that are so important in creating materials properties," Lindenberg said. "Until now, there have only been theoretical calculations of how these transformations should occur. Now we can learn firsthand what really happens."

Explore further: In-situ nanoindentation study of phase transformation in magnetic shape memory alloys

More information: "Real-Time Visualization of Nanocrystal Solid–Solid Transformation Pathways." Joshua S. Wittenberg, et al. Nano Lett., 2014, 14 (4), pp 1995–1999. DOI: 10.1021/nl500043c

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