Researchers see rare-earth-like magnetic properties in iron

Apr 28, 2014 by Paul Canfield
A single crystal of lithium-iron nitride is shown. Scientists at the US Department of Energy's Ames Laboratory observed magnetic properties in iron-ions in these lithium-iron nitrides that are typically associated with rare-earth elements. Credit: Ames Laboratory

( —Scientists at the Department of Energy's Ames Laboratory have observed magnetic properties typically associated with those observed in rare-earth elements in iron. These properties are observed in a new iron based compound that does not contain rare earth elements, when the iron atom is positioned between two nitrogen atoms. The discovery opens the possibility of using iron to provide both the magnetism and permanence in high-strength permanent magnets, like those used in direct-drive wind turbines or electric motors in hybrid cars. The results appeared in Nature Communications.

In modern magnets, iron gives most magnets their strength, and comes with the benefits of being abundant and cheap. But the magnet recipe must also include , which lend magnets "permanence," or the ability to keep the direction of the magnetic field fixed (also called anisotropy). The challenge is materials are expensive and at risk of domestic supply shortages. So, ideal next-generation permanent magnets will rely more heavily on iron or other abundant materials and less on rare earths.

"The breakthrough here is that we see anisotropy normally associated with rare earths ions in iron," said Paul Canfield, Ames Laboratory physicist. "This isn't an industrial breakthrough at this point because these only reveal themselves at cryogenic temperatures. But, it's a basic science breakthrough that hopefully will point the way to future technical breakthroughs."

Canfield's research group is internationally known for expertise in design, discovery, growth and characterization of new and promising materials. In this effort, Canfield and his colleagues, including postdoctoral research associate Anton Jesche, designed a new technique to grow lithium-iron-nitride single crystals from a lithium-nitrogen solution.

"Using nitrogen in solution growth had not yet been well explored because, since we typically think of nitrogen as a gas, it's challenging to get into a solution" said Jesche, "But we found that lithium – lightest solid element—looked like it could hold nitrogen in solution. So, we mixed together lithium and lithium-nitride powder, and it worked. It created a solution."

Then the group added in iron and, to their surprise, the iron dissolved.

"Usually iron and lithium don't mix," said Canfield, who is also a Distinguished Professor of physics and astronomy at Iowa State University. "It seems adding nitrogen to the lithium in the solution allows iron to go in."

The resulting single crystals of iron-substituted lithium nitride yielded even more surprises: the opposing external field required to reverse magnetization was more than 11 tesla, as much as an order of magnitude larger than that of commercially available permanent magnets and two or more orders of magnitude larger than is typically found in single crystals. Further evidence of iron's exotic state in this compound is the field-induced quantum tunneling found for very diluted iron concentrations at the relatively high temperature of 10 Kelvin, a temperature orders of magnitude higher than what had been seen before.

"With detailed measurements, we saw that these single iron ions are indeed behaving like a single rare-earth ion would," Canfield continued. "And we believe this has to do with the special, fairly simple, geometry that the iron finds itself in: one positioned between two . We hope this crystal growing technique and this specific material can be a model system for further theoretical study of these rare-earth-like ions. As it stands, these materials have clear implications on finding rare-earth-free replacements for permanent magnets—and perhaps also may impact data storage and manipulation in quantum computer applications."

Explore further: Can perovskites and silicon team up to boost industrial solar cell efficiencies?

More information: Paper:… full/ncomms4333.html

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Apr 28, 2014
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5 / 5 (1) Apr 29, 2014
Other magnets too are sensitive to temperature. The highest grade Nd magnets can temporarily lose strength simply by holding one in your hand, which is a technical limitation of the material because they can become completely demagnetized by overheating and eventually permanently so.

The stronger the magnet, the lower it's Curie temperature seems to be, so it's not surprising that a magnet that operates only at very low temperatures would be super strong.

not rated yet Apr 29, 2014
The stronger the magnet, the lower it's Curie temperature seems to be
Yep, strong magnet do share many common points with superconductors (just instead of mutually repulsive electrons they squeeze magnetic moments of unpaired electrons). The principles of exploitation of these systems for negentropic phenomena are therefore similar.

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