Researchers make major advances in dye sensitized solar cells

Apr 23, 2014
Researchers make major advances in dye sensitized solar cells
A set of figures illustrating the effect of applied voltage during electrolysis on the spacing between nanosheets (bottom) and the corresponding variations in electrical properties (top)

Working on dye-sensitized solar cells - researchers from University Malaya (UM) and National Tsing Hua University (NTHU) have achieved an efficiency of 1.12 %, at a fraction of the cost compared to those used by platinum devices.

This work has been accepted for publication in the journal, Nanoscale published by the Royal Society of Chemistry and has been selected for the front cover of the issue.

The study carried out in Taiwan took on the challenge of making the technology behind more affordable by replacing the costly platinum counter-electrodes with bismuth telluride (Bi2Te3) nanosheet arrays.

Using a novel electrolysis process, the group managed to closely manipulate the spacing between individual nanosheets and hence control the thermal and electrical conductivity parameters to achieve the high efficiency of 1.12%, which is comparable to platinum devices, but at only at a fraction of the cost.

The research was led by Prof. Yu-Lun Chueh of the Nanoscience & Nanodevices Laboratory, NTHU, and Alireza Yaghoubi, UM HIR Young Scientist. "In light of the recent report by the United Nations about the irreversible effects of fossil fuels on climate change and as we gradually run out of economically recoverable oil reserves, we think it is necessary to look for a sustainable, yet practical source of energy" Yaghoubi stated.

Meanwhile at University Malaya, Dr. Wee Siong Chiu and colleagues were working on controlling the secondary nucleation and self-assembly in zinc oxide (ZnO), a material which is currently being scrutinized for its potential applications in dye-sensitized as well as photocatalytic reactions to generate clean electricity by splitting water under sunlight.

In this work, Dr. Chiu and Alireza Yaghoubi demonstrated a new route for synthesis of various zinc oxide nanostructures using the lipophilic interactions between a novel precursor and a number of fatty acids. They are hoping to further use this method to increase the efficiency of photocatalysts in the visible regime where most of the sunlight energy lies.

According to the researchers, if this approach is successful, generating electricity is as easy as pouring some bioinert nanomaterials into a lake and fusing the split oxygen and hydrogen atoms back into water in a photoelectrochemical cell.

This paper will be on the front cover of CrysEngComm, also published by the Royal Society of Chemistry.

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More information: Hung-Wei Tsai, Tsang-Hsiu Wang, Tsung-Cheng Chan, Pei-Ju Chen, Chih-Chun Chung, Chien-Neng Liao, Alireza Yaghoubi, Eric Wei-Guang Diau, and Yu-Lun Chueh. "Fabrication of Large Scale Single Crystal Bismuth Telluride (Bi2Te3) Nanosheet Arrays by Single Step Electrolysis Process." Nanoscale (2014). DOI: 10.1039/C4NR00184B

W.S. Chiu, A. Yaghoubi, M.Y. Chia, N.H. Khanis, S.A. Rahman, P.S. Khiew, and Y.L. Chueh. "Self-assembly and secondary nucleation in ZnO nanostructures derived from a lipophilic precursor." CrystEngComm (2014). DOI: 10.1039/C4CE00442F

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