Researchers change coercivity of material by patterning surface

March 18, 2014 by Matt Shipman
By creating a corduroy pattern on the surface of NFO thin films, researchers have been able to lower the coercivity of the NFO by 30 to 80 percent, depending on the thickness of the film. Credit: Goran Rasic

( —Researchers from North Carolina State University have found a way to reduce the coercivity of nickel ferrite (NFO) thin films by as much as 80 percent by patterning the surface of the material, opening the door to more energy efficient high-frequency electronics, such as sensors, microwave devices and antennas.

"This technique reduces coercivity, which will allow devices to operate more efficiently, reducing energy use and improving performance," says Goran Rasic, a Ph.D. student at NC State and lead author of a paper describing the work. "We did this work on NFO but, because the reduced coercivity is a direct result of the patterning, we think our technique would work for other magnetic materials as well."

Coercivity is a property of magnetized materials and is the amount of magnetic field needed to bring a material's magnetization to zero. Basically, it's how much a material likes being magnetic. For devices that rely on switching current back and forth repeatedly – such as most consumer electronics – you want that have low coercivity, which improve device performance and use less energy.

Iron oxides, like NFO, have a variety of properties that are desirable for use in high-frequency devices, but they do have a down side: they have high coercivity. The new research from NC State helps address this problem.

By creating a corduroy pattern on the surface of NFO thin , researchers have been able to lower the coercivity of the NFO by 30 to 80 percent, depending on the thickness of the film. Thinner films experience a larger reduction in coercivity. The surface pattern on the NFO films consists of raised structures that are 55 nanometers (nm) high and 750 nm wide. The structures run parallel to each other and are spaced 750 nm apart, creating the corduroy effect.

Explore further: Magnetic memories manipulated by voltage, not heat

More information: Rasic, G.; Schwartz, J., "Coercivity Reduction in Nickel Ferrite (NiFe2O4) Thin Films Through Surface Patterning," Magnetics Letters, IEEE , vol.5, no., pp.1,4, 2014. DOI: 10.1109/LMAG.2014.2302246

NiFe2O4 (NFO), a spinel ferrite, with high electrical resistivity and favorable magnetic properties, is an interesting material for high-frequency signal and power electronic applications. Here, significant reduction in the coercivity of NFO films is obtained through surface patterning via nanoimprint lithography. Multilayered NFO films are grown on c-plane (0001) sapphire substrates using room temperature chemical solution deposition. Two film variants, layer-by-layer and bulk, are deposited. Prior to crystallization, films are patterned with a polydimethylsiloxane stamp. Good feature transfer to the thin film surface is confirmed by atomic force microscopy and transmission electron microscopy. X-ray diffraction shows both variants produce single phase inverse spinel NFO, with better texture in the layer-by-layer samples. Magnetic measurements show substantial reduction in coercivity in the patterned samples due to the surface anisotropy enhanced demagnetization field. The bulk patterned sample showed the lowest coercivity, ~18 Oe in-plane, albeit with reduced saturation magnetization, whereas the layer-by-layer patterned film maintained the same high degree of texture and saturation as unpatterned films, with a ~80% reduction in coercivity. These results show that nanoimprint lithography of chemical solution deposition films is a cost-effective pathway to engineering the magnetic behavior of NFO films of variable thickness.

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