How to tell when bubbly goes bad before popping the cork

Feb 05, 2014
How to tell when bubbly goes bad before popping the cork

In the rare case that New Year's revelers have a bottle of leftover bubbly, they have no way to tell if it'll stay good until they pop the cork and taste it at the next celebration. But now scientists are reporting a precise new way for wineries—and their customers—to predict how long their sparkling wines will last. The study appears in ACS' Journal of Agricultural and Food Chemistry.

Montserrat Riu-Aumatell and colleagues explain that the shelf life of various sparkling wines, from champagne to prosecco, depends on such as temperature. Currently, wineries detect the so-called browning of bubbly by measuring its "absorbance," or its absorption of light at a particular wavelength. It's a fast and easy technique but not very sensitive. Researchers exploring the chemistry of sparkling wine are turning to the food industry for alternatives. Food manufacturers can measure a compound called 5-HMF, which builds up in food as it goes bad, to tell when to toss a product out. Riu-Aumatell's team decided to see if they could use the compound, which is also found in bubbly, to predict the of sparkling wines.

They tested levels of this browning compound in several bottles stored over two years at different temperatures: room, cellar (61 degrees Fahrenheit) and refrigerator (39 degrees Fahrenheit). Their study found that 5-HMF is a good indicator of freshness, and also that refrigerating sparkling wines almost completely prevented browning. To make their results more practical for wineries, the researchers came up with a mathematical model that predicts how long products will stay drinkable at varying storage temperatures.

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More information: "Kinetics of Browning, Phenolics, and 5-Hydroxymethylfurfural in Commercial Sparkling Wines" J. Agric. Food Chem., 2014, 62 (5), pp 1159–1166
DOI: 10.1021/jf403281y

Abstract
We analyzed the degree of browning (absorbance at 420 nm), the phenolics, and the 5-hydroxymethylfurfural (5-HMF) content in six sparkling wines series kept at three temperatures (4, 16, and 20 °C) for over 2 years. Caffeic acid, trans-coutaric acid, p-coumaric acid, and 5-HMF were the compounds with the greatest correlation with browning and time. 5-HMF was the only compound that evolved linearly at all temperatures. We propose that 5-HMF is a better time–temperature marker than the A420 parameter or phenolics, because it shows higher linearity with time at all temperatures, is more sensitive to temperature changes, and has lower variability. The kinetics of 5-HMF was studied showing a zero-order behavior. We propose mathematical models that wineries can use to predict the browning shelf life of their sparkling wines as a function of the storage time and temperature.

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