Making silicon devices responsive to infrared light

Jan 06, 2014 by David L. Chandler
A laser beam is used in the lab to test the gold-hyperdoped sample of silicon to confirm its infrared-sensitive properties. Credit: MIT

Researchers have tried a variety of methods to develop detectors that are responsive to a broad range of infrared light—which could form imaging arrays for security systems, or solar cells that harness a broader range of sunlight's energy—but these methods have all faced limitations. Now, a new system developed by researchers at five institutions, including MIT, could eliminate many of those limitations.

The new approach is described in a paper published in the journal Nature Communications by MIT graduate student Jonathan Mailoa, associate professor of mechanical engineering Tonio Buonassisi, and 11 others.

Silicon, which forms the basis of most semiconductor and solar-cell technology, normally lets most infrared light pass right through. This is because the material's bandgap—a fundamental electronic property—requires an energy level greater than that carried by photons of infrared light. "Silicon usually has very little interaction with infrared light," Buonassisi says.

Various treatments of silicon can mitigate this behavior, usually by creating a waveguide with structural defects or doping it with certain other elements. The problem is that most such methods have significant negative effects on silicon's electrical performance; only work at very low temperatures; or only make silicon responsive to a very narrow band of infrared wavelengths.

The new system works at and provides a broad infrared response, Buonassisi says. It incorporates atoms of into the surface of silicon's crystal structure in a way that maintains the material's original structure. Additionally, it has the advantage of using silicon, a common semiconductor that is relatively low-cost, easy to process, and abundant.

The approach works by implanting gold into the top hundred nanometers of silicon and then using a laser to melt the surface for a few nanoseconds. The recrystallize into a near-perfect lattice, and the don't have time to escape before getting trapped in the lattice.

In fact, the material contains about 1 percent gold, an amount more than 100 times greater than silicon's solubility limit: Normally, this is as if one put more sugar into a cup of coffee than the liquid could absorb, leading to accumulation of sugar at the bottom of the cup. But under certain conditions, materials can exceed their normal solubility limits, creating what's called a supersaturated solution. In this case, the new processing method produces a layer of silicon supersaturated with gold atoms.

"It's still a , but it has an enormous amount of gold near the surface," Buonassisi says. While others have tried similar methods with materials other than gold, the MIT team's work is the first clear demonstration that the technique can work with gold as the added material, he says.

"It's a big milestone, it shows you can do this," Mailoa says. "This is especially attractive because we can show broadband infrared response in silicon at room temperature." While this is early-stage work, for some specialized purposes—such as a system for adjusting infrared laser alignment—it might be useful relatively quickly.

This use of gold was a surprise: Usually gold is incompatible with anything involving silicon, Buonassisi says. Even the tiniest particle of it can destroy the usefulness of a silicon microchip—so much so that in many chip-manufacturing facilities, the wearing of gold jewelry is strictly prohibited. "It's one of the most dangerous impurities in silicon," he says.

But at the very high concentrations achieved by laser doping, Buonassisi says, gold can have a net positive optoelectronic impact when shines on the device.

While this approach might lead to infrared imaging systems, Buonassisi says, its efficiency is probably too low for use in solar cells. However, this laser processing method might be applicable to different materials that would be useful for making , he says.

Explore further: Imec simplifies i-PERC solar cell processing by implementing laser doping from ALD-Al2O3

Related Stories

Engineers' nanoantennas improve infrared sensing

May 20, 2013

(Phys.org) —A team of University of Pennsylvania engineers has used a pattern of nanoantennas to develop a new way of turning infrared light into mechanical action, opening the door to more sensitive infrared ...

Solar cells made from black silicon

Oct 01, 2012

Solar cells convert three-quarters of the energy contained in the Sun's spectrum into electricity – yet the infrared spectrum is entirely lost in standard solar cells. In contrast, black silicon solar cells ...

Recommended for you

Ultrafast remote switching of light emission

1 hour ago

Researchers from Eindhoven University of Technology can now for the first time remotely control a miniature light source at timescales of 200 trillionth of a second. They published the results on Sept. 2014 ...

Nanotube cathode beats large, pricey laser

8 hours ago

Scientists are a step closer to building an intense electron beam source without a laser. Using the High-Brightness Electron Source Lab at DOE's Fermi National Accelerator Laboratory, a team led by scientist ...

User comments : 1

Adjust slider to filter visible comments by rank

Display comments: newest first

rsklyar
not rated yet Jan 07, 2014
Beware that a gang of MIT "researchers" has already stole in Nature journals and, with further support of the Harvard's ones, in ASC Nano Lett both the ideas and money of taxpayers. There are numerous swindlers from David H. Koch Inst. for Integrative Cancer Research and Dept of Chemical Engineering, also with Dept of Chemistry and Chem. Biology and School of Eng and Applied Science of Harvard University at http://issuu.com/...vard_mit & http://issuu.com/...llsens12 .
Their plagiaristic compilation titled Macroporous nanowire nanoelectronic scaffolds for synthetic tissues (DOI: 10.1038/NMAT3404) and Outside Looking In: Nanotube Transistor Intracellular Sensors (dx.doi.org/10.1021/nl301623p) was funded by NIH Director's Pioneer Award (1DP1OD003900) and a McKnight Foundation Technol Innovations in Neurosc Award, also a Biotechnology Research Endowment from the Dept. of Anesthesiology at Children's Hospital Boston and NIH grants GM073626, DE01-3023/6516.