In just seconds, low-cost porous organic polymer can cut toxic metal concentrations in water to inconsequential levels

Jan 15, 2014
Water purification: Heavy metals meet their match
Corroded plumbing systems can introduce heavy metal contaminants to drinking water, but a novel polymer sorbent can now remove such impurities within seconds. Credit: francesco turci/iStock/Thinkstock

Aquifers, lakes, and rivers that supply drinking water rarely contain metal contaminants. When water passes through service lines and home plumbing systems, however, corrosion can introduce small amounts of lead, cadmium and other heavy metals that are toxic to human health. Recently, the World Health Organization lowered the recommended lead concentrations in drinking water to 10 parts per billion (ppb) to help prevent accidental poisoning.

Reaching such low lead concentration levels typically requires time-consuming precipitation reactions or expensive reverse osmosis systems that also remove essential minerals, such as calcium, from . A team led by Yugen Zhang and Jackie Y. Ying from the A*STAR Institute of Bioengineering and Nanotechnology has now developed a technology that greatly improves purification efforts. They used a porous polymer that selectively binds to lead and other in flowing water.

Filtering water through porous substances, such as activated charcoal, is one of the oldest and most effective decontamination technologies. Over the past few decades, chemists have developed newer materials called porous organic polymers (POPs), which combine nanometer-scale pore sizes with highly tunable molecular building blocks. These attributes have made POPs appealing platforms for isolating and storing gases such as hydrogen and carbon dioxide, as well as catalytic supports.

Zhang, Ying and co-workers recently synthesized a POP known as mesoporous poly-melamine-formaldehyde (mPMF) with exceptional carbon-capture capabilities. The material has a high surface area arising from a chemical structure composed of nitrogen-bearing aromatic rings that link into larger, nanoscale loops through hydrocarbon-amine units. Because the nitrogen atoms found in this POP have a strong binding affinity for heavy metals, the team suspected that mPMF could also act as a sorbent for .

After a simple one-step reaction to create the inexpensive mPMF polymer, the researchers placed it into contaminated with an excess of lead ions. Remarkably, more than 99 per cent of the toxic metal was removed within 5 seconds, reducing the lead levels to part-per-trillion concentrations. Removal efficiencies were equally high in stationary and more challenging dynamic flow conditions. Furthermore, the team could recover the ions and recycle the sorbent using simple dilute acid treatments.

In-depth experiments revealed that mPMF's ultrafast adsorption behavior was due to an open porous structure that allows full access to nitrogen atom binding sites. These sites also removed heavy metals such as cadmium and palladium but had little affinity for calcium and potassium cations – a selectivity that could make an immediate impact in commercial applications.

Explore further: New method for efficient removal of uranium and other heavy metals from water

More information: Tan, M. X., Sum, Y. N., Ying, J. Y. & Zhang, Y. A mesoporous poly-melamine-formaldehyde polymer as a solid sorbent for toxic metal removal. Energy & Environmental Science 6, 3254–3259 (2013). dx.doi.org/10.1039/c3ee42216j

add to favorites email to friend print save as pdf

Related Stories

Carbon capture: Durable plastic doubles as a cleaner

Sep 25, 2013

Melamine, a small aromatic molecule loaded with nitrogen atoms, has traditionally found fame as a tough plastic that is ideal for making durable dishware and laminate coatings. Research by Mei Xuan Tan, Yugen ...

Recommended for you

Figuring out how we get the nitrogen we need

Oct 28, 2014

(Phys.org) —Nitrogen is an essential component of all living systems, playing important roles in everything from proteins and nucleic acids to vitamins. It is the most abundant element in Earth's atmosphere ...

Keeping hydrogen from cracking metals

Oct 28, 2014

Metal alloys such as steel and zirconium that are used in pipes for nuclear reactors and oil fields naturally acquire a protective oxide or sulfide layer. But hydrogen penetration can lead to their breakdown ...

User comments : 1

Adjust slider to filter visible comments by rank

Display comments: newest first

wealthychef
not rated yet Jan 15, 2014
"inexpensive" is relative. Anything is expensive if you need a lot of it. How much does it cost to purify a well? Also, can this be used as a way to "mine" metals from teh ocean?

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.