Study: Potential benefits of pinewood char as synthetic fuel source

Dec 19, 2013 by Phillip Fiorini
SEM images show pinewood sawdust (top) and char (below) using a Philips XL40 FESEM at 1,000 times magnification. The sawdust contains smooth surfaces divided by parallel walls. In contrast to the sawdust, the char surface appears rough because of randomly oriented fibers that exhibit significant wrinkling. Numerous wide tunnels protruding into the char particles are observed. These tunnels provide pathways for transport of CO2 into the particle. Credit: Purdue University image/Indraneel Sircar

(Phys.org) —Researchers at Purdue University have successfully tested the conversion of large particles of pinewood char in a gasification process, a step necessary for the mass production of synthetic liquid fuel from recalcitrant biomass.

The results, which will be published in the March edition of the journal Fuel, stemmed from a series of experiments using a new facility at Purdue's Maurice J. Zucrow Laboratories aimed at learning precisely how biomass is broken down in reactors called gasifiers as part of a project to strengthen the scientific foundations of the economy.

"The results of the study show that the apparent gasification rate parameters for relatively large particles of practical relevance are comparable to those obtained from laboratory studies with much smaller particles," said Purdue mechanical engineering doctoral student Indraneel Sircar, a graduate assistant at Zucrow Labs and paper co-author. "On a larger scale, this research is a small part in the goal of creating a more sustainable synthetic fuel economy."

Synthetic fuels currently are being blended with petroleum fuels for performance improvement in automobile and aircraft applications and also are used in equipment trials in commercial aircraft. New techniques, however, are needed to reduce the cost and improve the efficiency of making the fuels.

In the Purdue study, the researchers measured the rate parameters for pinewood char gasification with CO2, using large particles in relation to practical gasifiers.

The char was prepared by inert heating of a large quantity of low-ash pinewood sawdust in an electrical furnace to a temperature of 1,100 degrees Kelvin. The low-ash pinewood char was selected to minimize the catalytic effects of ash on mass-loss rates.

The researchers said char gasification for CO2 recycling was used because it has been studied less than char gasification in other environments and has the potential to reduce greenhouse gas emissions by recycling CO2 from stationary power plant exhaust streams.

They relied on independent measurements from gravimetric analyses and product gas composition analyses to determine char mass-loss rates and conducted detailed uncertainty analyses of both methods and reported uncertainties in kinetic rate parameters. They also investigated the char structure development with reaction progress and its implication on mass-loss rates.

Joining Sircar as authors of the paper are Purdue mechanical engineering doctoral students Anup Sane and Weichao Wang and Jay Gore, the Reilly University Chair Professor of Combustion Engineering.

"This study, specifically on the widely available pinewood, moves us a step closer toward mass producing this as a synthetic fuel for uses by the U.S. air transportation system, thereby reducing our reliance on petroleum oil," Gore said.

Purdue researchers also are using the facility at Zucrow Labs to learn how coal and biomass "gasify" under high pressure in order to improve the efficiency of the . Students are working on doctoral theses on the system's mechanical design, optical diagnostics and approaches for integrating aerospace-related technologies.

In addition, they hope to determine how to generate less carbon dioxide than conventional synthetic-fuel processing methods while increasing the yield of by adding hydrogen into the coal-and-biomass-processing reactor, a technique pioneered by Rakesh Agrawal, Purdue's Winthrop E. Stone Distinguished Professor of Chemical Engineering.

Findings published in 2009 showed that carbon dioxide might be reduced by 40 percent using the technique.

The research is part of a larger effort to develop a system for generating large quantities of synthetic fuel from agricultural wastes, other biomass or coal that would be turned into a gas and then converted into a liquid fuel.

Gore and Robert Lucht, the Ralph and Bettye Bailey Professor of Combustion in Mechanical Engineering at Purdue, are working with faculty from Purdue's schools of Aeronautics and Astronautics and Chemical Engineering and other Purdue faculty members.

The work is funded by the U.S. Air Force Office of Scientific Research and has been done in conjunction with the Purdue Energy Center, located in Discovery Park.

The Purdue Energy Center, part of the university's Global Sustainability Institute, is focused on advancing energy sciences and engineering for sustainable energy solutions. The Energy Center was launched in Discovery Park to coordinate Purdue's research efforts in sustainability challenges such as climate change, energy, food security, the environment and water.

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More information: Indraneel Sircar, Anup Sane, Weichao Wang, Jay P. Gore. "Experimental and modeling study of pinewood char gasification with CO2." Fuel, Volume 119, 1 March 2014, Pages 38-46, ISSN 0016-2361, dx.doi.org/10.1016/j.fuel.2013.11.026.

Abstract
The objective of this study is to measure apparent rate parameters for pinewood char gasification with CO2 using large particles with relevance to practical gasifiers. The novel features of this work include: (1) char gasification for CO2 recycling, which is studied less in the past than char gasification in other environments, (2) independent measurements involving gravimetric analyses and product gas composition gas chromatography, (3) detailed uncertainty analyses of both methods to report resulting uncertainties in kinetic rate constants, and (4) investigation of the char structure development and its role in gasification. A fixed-bed reactor providing a slip-velocity of 0.12 m/s gasifier and control of the bed temperature to within ±10 K at 1000–1170 K is used. A low-ash (<0.01 wt.%) pinewood char is selected to minimize the catalytic effects of ash on mass-loss rates. The char is prepared by heating pinewood sawdust in an electrical furnace to a temperature of 1100 K. Gravimetric and product gas composition data are interpreted using the volumetric, non-reactive core and random pore models. The results show that the activation energies corresponding to these models are 217 ± 6, 186 ± 13, 125 ± 30 kJ/mol, respectively. The random pore model shows the closest agreement with the experimental data, despite the uncertainties in the measured activation energies. The estimated random pore model structure parameter W increases from 0 to 16.5 with increases in the gasification temperature. Measurements of BET surface area show significant increase with char conversion. The results of this study show that the apparent gasification rate parameters for relatively large particles of practical relevance are comparable to those obtained from laboratory studies with much smaller particles.

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