Three-dimensional carbon goes metallic

November 6, 2013 by Sathya Achia Abraham
This shows 3D Metallic carbon with interlocking hexagons. Credit: Qian Wang, Ph.D.

A theoretical, three-dimensional (3D) form of carbon that is metallic under ambient temperature and pressure has been discovered by an international research team.

The findings, which may significantly advance carbon science, are published online this week in the Early Edition of the Proceedings of the National Academy of Sciences.

Carbon science is a field of intense research. Not only does carbon form the chemical basis of life, but it has rich chemistry and physics, making it a target of interest to material scientists. From graphite to diamond to Buckminster fullerenes, nanotubes and graphene, carbon can display in a range of structures.

But the search for a stable three-dimensional form of carbon that is metallic under , including temperature and pressure, has remained an ongoing challenge for scientists in the field.

Researchers from Peking University, Virginia Commonwealth University and Shanghai Institute of Technical Physics employed state-of-the-art theoretical methods to show that it is possible to manipulate carbon to form a three-dimensional metallic phase with interlocking hexagons.

"The interlocking of hexagons provides two unique features – hexagonal arrangement introduces metallic character, and the interlocking form with tetrahedral bonding guarantees stability," said co-lead investigator Puru Jena, Ph.D., distinguished professor of physics in the VCU College of Humanities and Sciences.

The right combination of these properties could one day be applied to a variety of technologies.

"Unlike high-pressure techniques that require three terapascals of pressure to make carbon metallic, the studied structures are stable at ambient conditions and may be synthesized using benzene or polyacenes molecules," said co-lead investigator Qian Wang, Ph.D., who holds a professor position at Peking University and an adjunct faculty position at VCU.

"The new metallic structures may have important applications in lightweight metals for space applications, catalysis and in devices showing negative differential resistance or superconductivity," Wang said.

According to Jena, the team is still early in its discovery process, but hope that these findings may move the work from theory to the experimental phase.

The study is titled, "Three-dimensional Metallic Carbon: Stable Phases with Interlocking Hexagons."

Explore further: Carbon nanowires obtained by tempering diamantane dicarboxylic acid inside carbon nanotubes

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lib
not rated yet Nov 06, 2013
The authors seem to be thoroughly confused about what 'thermodynamical stability' means. In the introduction they say that "The dynamic, thermodynamic, and mechanical stability of these unique phases are confirmed by a series of state-of-the-art theoretical calculations." By the end of the paper they admit that "In a wide temperature range, the T6-carbon is thermodynamically metastable compared with diamond and graphite but more stable than many other carbon
allotropes ..."

There are countless far more stable metastable carbon allotropes. The authors' main assertion that the proposed phases " may be synthesized chemically by using benzene or polyacenes molecules" is not supported by any data. One wonders how the paper got through the peer-review process in the PNAS-level journal.
salf
not rated yet Nov 08, 2013
I have trouble understanding what they mean by metallic. What properties make this metallic? Can anyone help me?

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