Impossible material with world record breaking surface area made by swedish researchers

Jul 17, 2013
The material Upsalite is shown at different scales. Credit: Uppsala University

A novel material with world record breaking surface area and water adsorption abilities has been synthesized by researchers from Uppsala University, Sweden. The results are published today in PLOS ONE.

The magnesium carbonate material that has been given the name Upsalite is foreseen to reduce the amount of energy needed to control environmental moisture in the electronics and drug formulation industry as well as in hockey rinks and ware houses. It can also be used for collection of toxic waste, chemicals or oil spill and in , for odor control and sanitation after fire.

In contrast to what has been claimed for more than 100 years in the scientific literature, we have found that amorphous magnesium carbonate can be made in a very simple, low-temperature process, says Johan Goméz de la Torre, researcher at the Nanotechnology and Functional Materials Division.

While ordered forms of magnesium carbonate, both with and without water in the structure, are abundant in nature, water-free disordered forms have been proven extremely difficult to make. In 1908, German researchers claimed that the material could indeed not be made in the same way as other disordered carbonates, by bubbling CO2 through an alcoholic suspension. Subsequent studies in 1926 and 1961 came to the same conclusion.

This is the material Upsalite that was supposed to be impossible to realize. Credit: Simon Ydhag

A Thursday afternoon in 2011, we slightly changed the synthesis parameters of the earlier employed unsuccessful attempts, and by mistake left the material in the reaction chamber over the weekend. Back at work on Monday morning we discovered that a rigid gel had formed and after drying this gel we started to get excited, says Johan Goméz de la Torre.

A year of detailed analysis and fine tuning of the experiment followed. One of the researchers got to take advantage of his Russian skill since some of the chemistry details necessary for understanding the reaction mechanism was only available in an old Russian PhD thesis.

After having gone through a number of state of the art materials characterization techniques it became clear that we had indeed synthesized the material that previously had been claimed impossible to make, says Maria Strømme, professor of nanotechnology and head of the nanotechnology and functional materials division.

The most striking discovery was, however, not that they had produced a new material but it was instead the striking properties they found that this novel material possessed. It turned out that Upsalite had the highest surface area measured for an alkali earth metal carbonate; 800 square meters per gram.

This places the new material in the exclusive class of porous, high materials including mesoporous silica, zeolites, metal organic frameworks, and carbon nanotubes, says Strømme.

In addition we found that the material was filled with empty pores all having a diameter smaller than 10 nano meters. This pore structure gives the material a totally unique way of interacting with the environment leading to a number of properties important for application of the material. Upsalite is for example found to absorb more water at low relative humidities than the best materials presently available; the hydroscopic zeolites, a property that can be regenerated with less energy consumption than is used in similar processes today.

This, together with other unique properties of the discovered impossible material is expected to pave the way for new sustainable products in a number of industrial applications, says Maria Strømme.

Explore further: Mirror-image forms of corannulene molecules could lead to exciting new possibilities in nanotechnology

More information: PLOS ONE DOI 10.1371/journal.pone.0068486.

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User comments : 7

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h20dr
5 / 5 (1) Jul 17, 2013
Is aerogel in this class?
drel
5 / 5 (7) Jul 18, 2013
"...and by mistake left the material in the reaction chamber over the weekend."

Upsalite? they should have called it Oopsalite!
tadchem
2.1 / 5 (7) Jul 18, 2013
The perfect cat litter!
MrVibrating
1.3 / 5 (9) Jul 18, 2013
800 square meters / gram! Incredible..
Whydening Gyre
1.4 / 5 (11) Jul 19, 2013
"...and by mistake left the material in the reaction chamber over the weekend."

Upsalite? they should have called it Oopsalite!


Ups is how they say Oops in Swedish.
Neinsense99
1 / 5 (9) Jul 20, 2013
"...and by mistake left the material in the reaction chamber over the weekend."

Upsalite? they should have called it Oopsalite!


Ups is how they say Oops in Swedish.

City in Sweden. Also a few other places when the second p is omitted. https://en.wikipe.../Uppsala
Kev_C
not rated yet Jul 22, 2013
Wonder what happens when a boat load of this stuff spills in a river? One way to stop floods I suppose. It would take some explaining if the process got somehow carried away. Especially when they 'accidentally' left some in the chamber. Accidents do happen I know but I rather worry about these novel inventions. They tend to come with a side serving of unforseen consequences.