Discovery of new material state counterintuitive to laws of physics

Jun 12, 2013 by Tona Kunz
Discovery of new material state counterintuitive to laws of physics
Pressure-induced transitions are associated with near 2-fold volume expansions. While an increase in volume with pressure is counterintuitive, the resulting new phases contain large fluid-filled pores, such that the combined solid + fluid volume is reduced and the inefficiencies in space filling by the interpenetrated parent phase are eliminated.

( —When you squeeze something, it gets smaller. Unless you're at Argonne National Laboratory.

At the suburban Chicago laboratory, a group of scientists has seemingly defied the laws of physics and found a way to apply pressure to make a material expand instead of compress/contract.

"It's like squeezing a stone and forming a giant sponge," said Karena Chapman, a at the U.S. Department of Energy laboratory. "Materials are supposed to become denser and more compact under pressure. We are seeing the exact opposite. The pressure-treated material has half the density of the original state. This is counterintuitive to the ."

Because this behavior seems impossible, Chapman and her colleagues spent several years testing and retesting the material until they believed the unbelievable and understood how the impossible could be possible. For every experiment, they got the same mind-bending results.

"The bonds in the material completely rearrange," Chapman said. "This just blows my mind."

This discovery will do more than rewrite the science text books; it could double the variety of porous framework materials available for manufacturing, health care and .

Scientists use these framework materials, which have sponge-like holes in their structure, to trap, store and filter materials. The shape of the sponge-like holes makes them selectable for specific molecules, allowing their use as , and compressible storage for of . By tailoring release rates, scientists can adapt these frameworks to deliver drugs and initiate for the production of everything from plastics to foods.

"This could not only open up to being porous, but it could also give us access to new structures for selectability and new release rates," said Peter Chupas, an Argonne chemist who helped discover the new materials.

The team published the details of their work in the May 22 issue of the Journal of the American Chemical Society in an article titled "Exploiting High Pressures to Generate Porosity, Polymorphism, And Lattice Expansion in the Nonporous Molecular Framework Zn(CN)2 ."

The scientists put zinc cyanide, a material used in electroplating, in a diamond-anvil cell at the Advanced Photon Source (APS) at Argonne and applied high pressures of 0.9 to 1.8 gigapascals, or about 9,000 to 18,000 times the pressure of the atmosphere at sea level. This high pressure is within the range affordably reproducible by industry for bulk storage systems. By using different fluids around the material as it was squeezed, the scientists were able to create five new phases of material, two of which retained their new porous ability at normal pressure. The type of fluid used determined the shape of the sponge-like pores. This is the first time that hydrostatic pressure has been able to make dense materials with interpenetrated atomic frameworks into novel porous materials. Several series of in situ high-pressure X-ray powder diffraction experiments were performed at the 1-BM, 11-ID-B, and 17-BM beamlines of the APS to study the material transitions.

"By applying pressure, we were able to transform a normally dense, nonporous material into a range of new porous materials that can hold twice as much stuff," Chapman said. "This counterintuitive discovery will likely double the amount of available porous framework materials, which will greatly expand their use in pharmaceutical delivery, sequestration, material separation and catalysis."

The scientists will continue to test the new technique on other .

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1 / 5 (1) Jun 12, 2013
Interesting. I wonder how the high pressure reactions compare to the process of making aerogel at STP. Sounds like it will refine the thinking of chemistry, but will it change the laws of physics?
1 / 5 (2) Jun 12, 2013
The auxetic behaviour (giant negative compressibility) is typical for many compounds with cyanide coordination linkage.
1 / 5 (1) Jun 13, 2013
What a fascinating property. I wonder if it relates to water's behavior in freezing?
1 / 5 (2) Jun 16, 2013
Hit it with a massive electrostatic charge.

It will shrink back to it's original size.

Clear the building... and only do it with a gram of the material. Things might get stranger yet.

Correlation: Reference search - 'Farrell + Xerum 525'
1 / 5 (1) Jun 18, 2013
there are no laws of physics. only reproducible regularities which can be modeled in mathematical equations homomophic to physical observed phenomena. or alternately the laws of physics are frequently repealed