Thin films of nickel and iron oxides yield efficient solar water-splitting catalyst

March 20, 2013

University of Oregon chemists say that ultra-thin films of nickel and iron oxides made through a solution synthesis process are promising catalysts to combine with semiconductors to make devices that capture sunlight and convert water into hydrogen and oxygen gases.

Researchers in the Solar Materials and Electrochemistry Laboratory of Shannon Boettcher, professor of chemistry, studied the catalyst material and also developed a computer model for applying catalyst thin films in solar water-splitting devices as a tool to predict the effectiveness of a wide range of catalyst materials for solar-.

The project has resulted in two recent papers.

The first, detailed last September in the Journal of the American Chemical Society, showed that films of a nickel-iron mixed oxide with an atomic structure similar to naturally occurring minerals show the highest catalytic activity for forming oxygen from water, based on a side-by-side comparison of eight oxide-based materials targeted in various research efforts. The second paper, just published in the Journal of Physical Chemistry Letters, details the performance of the catalyst when combined with semiconductor light absorbers, showing that the nickel-iron oxide catalyst was most effective with a film just 0.4 nanometers thick.

Boettcher's lab, located in the UO's Materials Science Institute, studies fundamental and physical concepts related to the conversion of solar photons (sunlight) into electrons and holes in semiconductors that can then be used to drive chemical processes such as splitting protons off water to make hydrogen and oxygen gases. Multiple labs across the country are seeking effective and economical ways of taking sunlight and directly producing as an alternative sustainable fuel to replace fossil fuels.

"When you want to pull the protons off a water molecule to make hydrogen gas for fuel, you also have to take the leftover and make oxygen gas out of them," Boettcher said. "It turns out that the slowest, hardest, most-energy-consuming step in the water-splitting process is actually the oxygen-making step. We've been studying catalysts for making oxygen. Specifically, we're seeking catalysts that reduce the amount of energy it takes in this step and that don't use expensive precious metals."

The iron-nickel oxides, he said, have higher catalytic activity than the precious-metal-based catalytic materials that have been thought to be the best for the job.

"What we found is that when we take nickel oxide films that start out as a crystalline material with the rock-salt structure like table salt, they absorb iron impurities and spontaneously convert into materials with a layered structure during the catalysis process," Boettcher said.

Lena Trotochaud, a doctoral student and lead author on both papers, studied this process and how the films can be combined with semiconductors. "The semiconductors absorb the light, generating electron-hole pairs which move onto the catalyst material and proceed to drive the reaction, creating fuel," Boettcher said.

The computer modeling was used to understand how the amount of sunlight that the catalyst blocks from reaching the semiconductor can be minimized while simultaneously speeding up the reaction with water to form oxygen gas. This basic discovery remains a lab accomplishment for now, but it could advance to testing in a prototype device, Boettcher added.

"We're now looking at the fundamental reasons why these materials are good," Trotochaud said. "We are trying to understand how the catalyst works by focusing on the chemistry that is happening, and then also recognizing how that fits into a real system. Our research is fundamentally guiding how you would take these catalysts and incorporate them into something that is useful for everyone in society."

One such place the material could land in a prototype for testing is at the U.S. Department of Energy's Joint Center for Artificial Photosynthesis, an Energy Innovation Hub. The DOE supported Boettcher's research done in the second study through a Basic Sciences Energy grant (DE-FG02-12ER16323).

"This research holds great potential for the development of more efficient, more sustainable solar-fuel generation systems and other kinds of transformative energy technology," said Kimberly Andrews Espy, vice president for research and innovation and dean of the graduate school. "By seeking to advance carbon-neutral energy technology, Dr. Boettcher and his team are helping to establish Oregon as an intellectual and economic leader in fostering a sustainable future for our planet and its people."

Explore further: Efficient Catalysts for Making Oxygen for 'Artificial Photosynthesis'

Related Stories

Secrets of the first practical artificial leaf

May 9, 2012

A detailed description of development of the first practical artificial leaf — a milestone in the drive for sustainable energy that mimics the process, photosynthesis, that green plants use to convert water and sunlight ...

Improving performance of a solar fuel catalyst

October 4, 2012

(—Hydrogen gas that is created using solar energy to split water into hydrogen and oxygen has the potential to be a cost-effective fuel source if the efficiency of the catalysts used in the water-splitting process ...

Researchers harness nature to produce the fuel of the future

January 30, 2013

Hydrogen has tremendous potential as an eco-friendly fuel, but it is expensive to produce. Now researchers at Princeton University and Rutgers University have moved a step closer to harnessing nature to produce hydrogen for ...

Recommended for you

Scientists create revolutionary material to clean oil spills

November 30, 2015

Deakin University scientists have manufactured a revolutionary material that can clean up oil spills, which could save the earth from potential future disasters such as any repeat of the 2010 Gulf Coast BP disaster that wreaked ...

A new form of real gold, almost as light as air

November 25, 2015

Researchers at ETH Zurich have created a new type of foam made of real gold. It is the lightest form ever produced of the precious metal: a thousand times lighter than its conventional form and yet it is nearly impossible ...

1 comment

Adjust slider to filter visible comments by rank

Display comments: newest first

not rated yet Mar 28, 2013
I think the band wagon for Hydrogen as a transportation fuel is mostly out of steam now. With current Li-ion batteries beating out near best case future scenarios for fuel cell efficiency I'm not so sure anything hydrogen is going to be "transformative".

But hydrogen will always be an important industry manufacturing gas and once the fossil fuel industry wanes there will be greater demand for other sources.

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.