Researchers trap light, improve laser potential of MEH-PPV polymer

Mar 18, 2013

(Phys.org) —Researchers from North Carolina State University have come up with a low-cost way to enhance a polymer called MEH-PPV's ability to confine light, advancing efforts to use the material to convert electricity into laser light for use in photonic devices.

"Think of a garden hose. If it has holes in it, water springs out through a million tiny leaks. But if you can eliminate those leaks, you confine the water in the hose and improve the water pressure. We've plugged the holes that were allowing light to leak out of the MEH-PPV," says Dr. Lewis Reynolds, a teaching associate professor of at NC State and co-author of a paper describing the research.

MEH-PPV is a low-cost polymer that can be integrated with , and researchers have long sought to use the material to convert electricity into laser light for use in such as and . However, attempts to do this have failed because the amount of electricity needed to generate laser light in MEH-PPV was so high that it caused the material to degrade.

Now researchers have developed an inexpensive way to confine more light in the material, which lowers the energy threshold needed to produce focused laser light by 50 percent. The researchers did this by sandwiching the MEH-PPV between two materials that have matching indices of refraction, efficiently reflecting light back into the MEH-PPV and preventing light from escaping. This results in lower thresholds for .

"This approach is fairly inexpensive and could also be easily scaled up for large-scale processing," Reynolds says.

The "sandwich" also makes the material more stable by limiting the MEH-PPV's exposure to oxygen. This makes the material less subject to degradation due to photo-oxidation, which occurs when materials are exposed to both light and oxygen.

"This is a meaningful step forward for low-cost fabrication of these devices, but further optimization is required," says Dr. Zach Lampert, a former Ph.D. student at NC State and lead author of the paper. "We're working on that now."

Explore further: 'Dressed' laser aimed at clouds may be key to inducing rain, lightning

More information: The paper, "Enhancement of optical gain and amplified spontaneous emission due to waveguide geometry in the conjugated polymer poly[2-methoxy-5-(2'-ethylhexyloxy)-p-phenylene vinylene]," is published online in Applied Physics Letters: apl.aip.org/resource/1/applab/v102/i7/p073303_s1

Abstract
We report enhanced amplified spontaneous emission (ASE) and optical gain performance in a conjugated polymer (CP)-based thin film waveguide (WG) Si(100)/SiO2/poly[2-methoxy-5-(20-ethylhexyloxy)-p-phenylene vinylene] (MEH-PPV) by encapsulating the active layer with a transparent dielectric film of poly(methyl methacrylate) (PMMA). With index matched SiO2 and PMMA claddings, symmetric WGs are formed that exhibit increased mode confinement and reduced propagation loss enabling lower ASE threshold (40%) and higher optical gain (50%) compared to Si(100)/SiO2/MEH-PPV/air asymmetric WGs. An extremely large net gain coefficient of 500 cm_1 is achieved under picosecond pulse excitation, which is >4_ larger than values previously reported in the literature. Fabrication of symmetric WGs requires no complex processing techniques, thus offering a simple, low-cost approach for effectively controlling the ASE behavior of CP-based WGs and related optical devices.

Related Stories

Nanocomposite material provides photonic switching

Feb 09, 2009

(PhysOrg.com) -- Integrated photonic devices represent the wave of future technology. These devices will be extremely small, making use of photons on the nanoscale, and (hopefully) be very efficient in terms of power use. ...

How 'random' lasers work

Jan 24, 2010

When University of Utah scientists discovered a new kind of laser that was generated by an electrically conducting plastic or polymer, no one could explain how it worked and some doubted it was real. Now, ...

Research opens doors to UV disinfection using LED technology

May 14, 2012

Research from North Carolina State University will allow the development of energy-efficient LED devices that use ultraviolet (UV) light to kill pathogens such as bacteria and viruses. The technology has a wide array of applications ...

Recommended for you

Robotics goes micro-scale

Apr 17, 2014

(Phys.org) —The development of light-driven 'micro-robots' that can autonomously investigate and manipulate the nano-scale environment in a microscope comes a step closer, thanks to new research from the ...

High power laser sources at exotic wavelengths

Apr 14, 2014

High power laser sources at exotic wavelengths may be a step closer as researchers in China report a fibre optic parametric oscillator with record breaking efficiency. The research team believe this could ...

User comments : 0

More news stories

Could 'Jedi Putter' be the force golfers need?

Putting is arguably the most important skill in golf; in fact, it's been described as a game within a game. Now a team of Rice engineering students has devised a training putter that offers golfers audio, ...

Health care site flagged in Heartbleed review

People with accounts on the enrollment website for President Barack Obama's signature health care law are being told to change their passwords following an administration-wide review of the government's vulnerability to the ...

Airbnb rental site raises $450 mn

Online lodging listings website Airbnb inked a $450 million funding deal with investors led by TPG, a source close to the matter said Friday.