Researchers analyse interfaces between water and catalyst with computer simulations

Feb 21, 2013
Researchers analyse interfaces between water and catalyst with computer simulations
Snapshot of the charge transfer: Water-induced charge transfer at the interface between water and catalyst. The red and blue areas in the left and right image quantify the decrease or increase of the electron density due to the charge transfer at a given time. The blue and red mesh in the lower image section represents the oxide, the grey and yellow balls at the oxide surface the metal. The small blue and red molecules in the upper image section are water molecules. Credit: M. Farnesi Camellone, D. Marx

(—Why certain catalyst materials work more efficiently when they are surrounded by water instead of a gas phase is unclear. RUB chemists have now gleamed some initial answers from computer simulations. They showed that water stabilises specific charge states on the catalyst surface. "The catalyst and the water sort of speak with each other" says Professor Dominik Marx, depicting the underlying complex charge transfer processes. His research group from the Centre for Theoretical Chemistry also calculated how to increase the efficiency of catalytic systems without water by varying pressure and temperature.

The researchers describe the results in the journals Physical Review Letters and Letters.

Heterogeneous catalysis: water or gas as the second phase

In heterogeneous catalysis, researchers combine substances with two different phases - usually solid and gas. Chemical reactions work faster at the resulting interfaces than without a catalyst. Industry uses heterogeneous catalysis for many processes, for example to transform alcohols into certain aldehydes. with bonded to the surface, for example, is suitable as the solid phase. Water - instead of a gas - as the second phase has several advantages: environmentally harmful substances which are required in traditional procedures for the oxidation of alcohols can easily be replaced by . Also, the whole reaction in water is very efficient, even at moderate temperatures.

Charge transfer between water and catalyst

The theoretical chemists have studied what happens in the catalysis at the molecular level by means of so-called ab initio . The result: a charge transfer takes place between the water and the catalyst. Electrons, or more specifically portions of electron densities, are moved between the solid and the . The researchers speculate that in this way the liquid phase stabilises charge states on the gold surface. The sites where this occurs could be the active centres of the catalyst, where the chemical reactions work efficiently. Unlike water, a gas phase is not able to "talk" to the catalyst in this way, because no charge transfer is possible with the gas phase.

Increasing the efficiency through thermodynamics

In a further study, the team led by Dominik Marx examined a related metal/oxide catalyst of copper and zinc oxide, which is used for the large-scale industrial synthesis of methanol. As the showed, especially the interplay between the solid phase and the gas phase is important here for the efficiency. Depending on the pressure and temperature conditions, hydrogen binds to the catalyst surface and thus indirectly stabilises catalytically active centres that occur in this case due to an electron transfer between the metal and the oxide. "Without the hydrogen, put bluntly the centres would not exist", says Marx. In this way, the thermodynamic conditions in the gas phase put the surface into a certain state which is particularly favourable for the work of the catalyst.

Added value through combination

The two studies thus show that the catalytic efficiency can be controlled both by a solvent and by thermodynamics – namely through the pressure and temperature of the gas phase. However, completely different mechanisms are responsible for this, which the researchers were nevertheless able to elucidate using the same simulation methods. This makes the results directly comparable. In this way, the theorists aim to study in future whether they can improve the copper/zinc oxide system even further by replacing the gas phase with a suitable solvent.

Explore further: Research pinpoints role of 'helper' atoms in oxygen release

More information: Camellone, M. and Marx, D. (2013). On the impact of solvation on a Au/TiO2 nanocatalyst in contact with water, The Journal of Physical Chemistry Letters, doi: 10.1021/jz301891v

Martinez-Suarez, L. et al. (2013): Tuning the reactivity of a Cu/ZnO nanocatalyst via gas phase pressure, Physical Review Letters, doi: 10.1103/PhysRevLett.110.086108

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