Photon amplification, emission observed in plastic scintillation materials

January 8, 2013

A research team has observed, in polystyrene-based scintillation materials, photon amplification and emission that cannot be explained with the established scintillation mechanism. Photon yield from the polystyrene-based scintillation materials was found to increase in accordance with a power-law of concentration of fluorescent molecules doped in polystyrene.

The results of this research can have a variety of applications such as environmental / radiation measurements and elementary particle / experiments, and it requires new interpretations of the scintillation mechanism in plastic scintillation materials, which are expected to have further applications in the future. It is also expected to help to develop high performance .

The results of this research were published in Applied Physics Letters, the weekly journal of the , on December 28, 2012.

Plastic scintillation materials made by doping fluorescent molecules to plastics have been used in a wide variety of applications in order to obtain high sensitivity in detecting radiation. The scintillation mechanism of these materials was established in the middle of 20th century and it is explained with the so-called "ladder", in which ultra violet light emitted from plastics by radiation is converted stepwise into visible light by fluorescent molecules. This means that fluorescent molecules whose absorption wavelength overlaps with the emission wavelengths of plastics are required in making plastic scintillation materials.

In order to develop high performance plastic scintillation materials, the team focused on polystyrene, which emits when exposed to . In a departure from the established prerequisites, para-terphenyl was used as fluorescent molecule despite the fact that its absorption wavelength has a small overlap with the emission wavelength of polystyrene.

In the established scintillation mechanism, light emitted from plastics should be absorbed by fluorescent molecules and the light should be attenuated every time when it is re-emitted. In addition, when the relation between emission wavelength of polystyrene and absorption wavelength para-terphenyl is taken into account, photon yield emitted from polystyrene-based scintillation materials should be smaller than photon yield emitted from polystyrene having no fluorescent molecules added.

However, the photon yield emitted from the polystyrene-based scintillation materials is found to be more than that from having no fluorescent molecules added (see the figure on the left). In other words, the birth of new luminescence was shown. Furthermore, it is clearly shown (in the figure on the right) that photon yield from the scintillation material increases in accordance with a power-law of fluorescent molecule concentration (which is changed to the maximum of 5-orders). These phenomena cannot be explained with the present scintillation mechanism of plastic scintillation materials and requires new interpretations.

The product of this research will lead the way to the improved performance of radiation detectors which use a plastic scintillation material is used for such applications as natural environmental radiation / radiation measurements and / atomic nucleus experiments.

Explore further: Study Finds that Styrofoam Increases Biodiesel Power Output

More information: Nakamura, H. et al. Development of polystyrene-based scintillation materials and its mechanisms, Applied Physics Letters, 101, 261110 (2012).

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