To make better fuel cells, study the defects

Feb 20, 2012 By Bill Steele
When Amplex Red connects with a gold catalyst the structure is changed to make a fluorescent molecule that immediately emits a flash of light, showing where the catalytic event took place. Right, electron microphoto of a single gold nanorod, encased in a poirus silica shell. The shell keeps rods from clumping together and allows experimenters to use heat to clean away a coating that forms when the rods are created. Image: Chen Lab

Engineers trying to improve fuel-cell catalysts may be looking in the wrong place, according to new research at Cornell.

There is growing interest in forming the catalysts that break down fuel to generate electricity into . Nanoparticles provide a larger surface area to speed reactions, and in some cases, materials that are not catalytic in bulk become so at the .

These nanoparticles, typically just a few tens of nanometers (nm) wide, are not neat little , but rather jagged chunks, like microscale gravel, and researchers have found that they can correlate with information about the number and type of their surface facets. But they may be looking at the forest and ignoring the trees.

"People measure the activity of a sample and then try to understand by using facet information," said Peng Chen, associate professor of chemistry and . "The message we want to deliver is that surface defects [on the facets] dominate the ."

Chen's research is reported Feb. 19 in the online edition of the journal Nature Nanotechnology.

Instead of particles, Chen's research group studied catalytic events on gold "nanorods" up to 700 nm long, effectively letting them see how activity varies over a single facet. Gold acts as a to convert a chemical called Amplex Red into resorufin, which is fluorescent.

Each time a catalytic event occurs, the newly created molecule of resorufin emits a flash of light that is detected by a digital camera looking through a microscope. A flash typically appears as several pixels, and additional averages their brightness to pinpoint the actual event to within a few nanometers. The researchers call the technique "super-resolution microscopy." After flooding a field of nanorods with a solution of Amplex Red, they made a "movie" with one frame every 25 milliseconds.

The researchers found more catalytic events near the middle of a rod, tapering off toward the ends and a jump back up at the ends. They also found variation in the amount of activity from one rod to another, even though all the rods have the same types of facets.

To explain the results, they proposed that activity is higher in areas where there are more surface defects. The nanorods are made by growing gold crystals from a small "seed" crystal, growing outward from the center to the ends, Chen explained, and more defects form at the beginning of the process.

"Knowledge of the surface facets ... is insufficient to predict reactivity," the researchers said in their paper. "Surface defects … can also play a dominant role."

The findings with a gold catalyst and fluorescent molecules should be equally applicable to other catalysts, including those used in fuel cells and for pollution remediation, Chen said.

Explore further: Mirror-image forms of corannulene molecules could lead to exciting new possibilities in nanotechnology

Related Stories

Pinpointing catalytic reactions on carbon nanotubes

Apr 17, 2009

(PhysOrg.com) -- Among their many other interesting properties, carbon nanotubes have been found to act as catalysts for some important chemical reactions, including some that could be used to make cleaner ...

Platinum nanocatalyst could aid drugmakers

Aug 31, 2009

(PhysOrg.com) -- Nanoparticles combining platinum and gold act as superefficient catalysts, but chemists have struggled to create them in an industrially useful form. Rice University chemists have answered the call this week ...

Improving catalysis

Jun 14, 2011

(PhysOrg.com) -- Cardiff University research may help to improve the way that metal nanoparticles are used in catalysis – the process of making chemical reactions go faster.

Purdue finding could help develop clean energy technology

Mar 16, 2005

Chemical engineers at Purdue University have made a discovery that may help to improve a promising low-polluting energy technology that combusts natural gas more cleanly than conventional methods. The finding revolves aro ...

Recommended for you

Tiny graphene drum could form future quantum memory

Aug 28, 2014

Scientists from TU Delft's Kavli Institute of Nanoscience have demonstrated that they can detect extremely small changes in position and forces on very small drums of graphene. Graphene drums have great potential ...

Graphene reinvents the future

Aug 27, 2014

For many scientists, the discovery of one-atom-thick sheets of graphene is hugely significant, something with the potential to affect just about every aspect of human activity and endeavour.

User comments : 1

Adjust slider to filter visible comments by rank

Display comments: newest first

Isaacsname
not rated yet Feb 20, 2012
Well, you'd think that capitalizing on defects is the most effective way to improve a system, no ?