Study raises questions on what causes silicon solar cell degradation

The researchers, L. I. Murin, et al., from institutions in Belarus, the UK, Norway, Sweden, and Portugal, have published their study in a recent issue of Applied Physics Letters.

Several previous studies have predicted that the light-induced degradation of silicon solar cells is related to O_2i interacting with substitutional boron atoms to form a B_sO_2i complex. This B_sO_2i complex can act as a powerful recombination center that can cause solar cell degradation.

Previous research has suggested that doubly positively charged O_2i can capture an electron that has been optically excited by incoming photons in p-type silicon, and that this event triggers a migration step via the Bourgoin-Corbett mechanism. In this mechanism, the O_2i’s motion is driven by transitioning between different charge states. So the mechanism requires the existence of two stable configurations of O_2i in different charge states.

Previous ab initio modeling studies have suggested the existence of two stable configurations of the dimer in silicon crystals with different doping: in n-type silicon, the dimer is in a neutral charge state, and in p-type silicon, the dimer has been calculated to be in the doubly positively charged state.

So far, O_2i has been detected in the neutral charge state, but never in the doubly positively charged state in any silicon material, although it has been predicted by theoretical modeling. In the current study, the researchers have performed a systematic experimental search for the absorption signature of the doubly positively charged O_2i by carrying out infrared absorption measurements on n- and p-type silicon, including those in which light-induced degradation attributed to BsO2i has been observed.

The researchers performed their own ab initio calculations to get a clue as to the possible location of local vibrational mode lines due to the doubly positively charged O_2i. The calculations also revealed the expected intensity of the dimer’s local vibrational modes for both the neutral and doubly positively charged states.

However, the researchers found no trace of the doubly positively charged O_2i in their sample set. Although their data did show the existence of the O_2i in the neutral charge state, the Bourgoin-Corbett diffusion mechanism cannot occur without dimers in both charge states.

Overall, the results cast doubt on the formation of the B_sO_2i complexes that have been widely thought to cause light-induced degradation of silicon solar cells. The findings also suggest that alternative mechanisms for solar cell degradation deserve a closer look.

More information: L. I Murin, et al. “The oxygen dimer in Si: Its relationship to the light-induced degradation of Si solar cells?” Applied Physics Letters 98, 182101 (2011). DOI:10.1063/1.3584138

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