Less is more: Researchers pinpoint graphene's varying conductivity levels

Apr 18, 2011

(PhysOrg.com) -- Did you know that pencil lead may just end up changing the world? Graphene is the material from which graphite, the core of your No. 2 pencil, is made. It is also the latest "wonder material," and may be the electronics industry’s next great hope for the creation of extremely fast electronic devices. Researchers at North Carolina State University have found one of the first roadblocks to utilizing graphene by proving that its conductivity decreases significantly when more than one layer is present.

Graphene’s structure is what makes it promising for electronics. Because of the way its carbon atoms are arranged, its electrons are very mobile. Mobile electrons mean that a material should have high conductivity. But NC State physicist Dr. Marco Buongiorno-Nardelli and NC State electrical and computer engineer Dr. Ki Wook Kim wanted to find a way to study the behavior of “real” graphene and see if this was actually the case.

“You can talk about the electronic structure of graphene, but you must consider that those electrons don’t exist alone in the material,” Buongiorno-Nardelli says. “There are impurities, and most importantly, there are vibrations present from the atoms in the material. The electrons encounter and interact with these vibrations, and that can affect the material’s conductivity.”

Buongiorno-Nardelli, Kim and graduate students Kostya Borysenko and Jeff Mullen developed a computer model that would predict the actual conductivity of graphene, both as a single layer and in a bilayer form, with two layers of graphene sitting on top of one another. It was important to study the bilayer model because actual electronic devices cannot work with only a single layer of the material present.

“You cannot make a semiconductor with just one layer,” Buongiorno-Nardelli explains. “To make a device, the conductive material must have a means by which it can be turned off and on. And bilayer provides such ability.”

With the help of the high performance computers at Oak Ridge National Laboratories, the NC State team discovered both good and bad news about graphene. Their results appear as an Editor’s Suggestion in the April 15 edition of Physical Review B.

With a single layer of graphene, the mobility – and therefore conductivity – shown by the researchers’ simulations turned out to be much higher than they had originally thought. This good news was balanced, however, by the results from the bilayer state.

“We expected that the electrons’ in bilayer graphene could be somewhat worse, due to the ways in which the vibrations from the atoms in each individual layer interact with one another,” Mullen says. “Surprisingly, we found that the mobility of in bilayer graphene is roughly an order of magnitude lower than in a single graphene sheet.”

“The reduction is substantial, but even this reduced number is higher than in many conventional semiconductors,” Borysenko adds.

Buongiorno-Nardelli says that the NC State researchers are turning their attention to remedying this problem.

“If we put the graphene on a substrate that can ‘siphon off’ some of the heat generated by the electric current, the crystal vibrations will decrease and the mobility will increase. Those are our next steps – running the simulations with and substrates that have this property.”

Explore further: Nanoribbon film keeps glass ice-free: Team refines deicing film that allows radio frequencies to pass

More information: “Electron-Phonon Interactions in Bilayer Graphene” K. Borysenko, J.T. Mullen, K.W. Kim, et al, North Carolina State University, Published: April 15, 2011 in Physical Review B

Abstract:

Using calculations from first principles, we demonstrate that intrinsic carrier-phonon scattering in bilayer graphene is dominated by low energy acoustic (and acoustic-like) phonon modes in a framework that bears more resemblance with bulk graphite than monolayer graphene. The total scattering rate at low/moderate electron energies can be described by a simple two-phonon model in the deformation potential approximation with effective constants Dac ≈ 15 eV and Dop ≈ 2:8 × 108 eV/cm for acoustic and optical phonons, respectively. With much enhanced acoustic phonon scattering, the mobility of intrinsic bilayer graphene is estimated to be significantly smaller than that of monolayer.

Related Stories

Toward a better understanding of bilayer graphene

Oct 26, 2010

(PhysOrg.com) -- "Graphene is a very exciting material with a number of interesting possibilities, including for use in electronic devices," Pablo Jarillo-Herrero tells PhysOrg.com. "However, all graphene system ...

Damaging graphene to create a band gap

Nov 22, 2010

(PhysOrg.com) -- "Graphene offers a lot of interesting potential applications for nanoelectronics," Florian Banhart tells PhysOrg.com, "but there is no band gap. This is a well-known problem. Without the band gap, switch ...

Creating a pure spin current in graphene

Feb 07, 2011

(PhysOrg.com) -- Graphene is a material that has the potential for a number of future applications. Scientists are interested in using graphene for quantum computing and also as a replacement for electronics. However, in ...

The noise about graphene

Oct 15, 2010

(PhysOrg.com) -- In last week’s announcement of the Nobel Prize in Physics, the Royal Swedish Academy of Sciences lauded graphene’s "exceptional properties that originate from the remarkable world ...

Recommended for you

Twisted graphene chills out

5 hours ago

(Phys.org) —When two sheets of graphene are stacked in a special way, it is possible to cool down the graphene with a laser instead of heating it up, University of Manchester researchers have shown.

Researchers use liquid inks to create better solar cells

5 hours ago

(Phys.org) —The basic function of solar cells is to harvest sunlight and turn it into electricity. Thus, it is critically important that the film that collects the light on the surface of the cell is designed ...

User comments : 0