Researchers use electron beams for chemical reactions

Apr 13, 2011
The principle of the local deposition process which is induced with a focussed electron beam (in short, FEBIP): molecules from a gas-injection system are deposited on the sample surface in a reversible manner. The focussed electron beam dissociates adsorbed gas molecules. The resulting non-volatile compounds remain permanently on the sample.

Electron microscopes use focussed electron beams to make extremely small objects visible. By combining the instrument with a gas-injection system material samples can be manipulated and surface structures measuring only nanometres across can be "written". Swiss researchers at EMPA, together with scientists from EPFL, used this method to improve lasers.

The vertical cavity surface emitting laser (VCSEL) is a semiconductor laser which is often used in data transmission for short-distance links like Gigabit Ethernet. These lasers are very popular in telecommunications because they consume little energy and can be simply fabricated in volumes of many tens of thousands on a single wafer. However, these VCSELs can exhibit one weakness: Because of the cylindrical structure in which the lasers are built up on the wafer, the polarisation of the emitted light can sometimes change during operation. Polarisation is a property of certain waves, such as , and it describes the direction of oscillation. A stable polarisation is necessary in order to reduce transmission errors and to use VCSELs in future .

The team led by Empa researcher Ivo Utke, together with scientists from the Laboratory of Physics of at EPFL, could provide assistance by using a method called FEBIP (focussed induced processing). “We’ve written flat grating structures on the VCSELs with an electron beam,” says Utke in describing their solution, “and the gratings were effective in stabilising the polarisation.” The study has recently been published in the scientific journal “Nanoscale” as an advanced online publication.

The result is a nanostructure - for example a polarisation grating on a VCSEL (vertical cavity surface emitting laser). These are semiconductor lasers frequently used in optical data transmission.

Small, minimally invasive, direct

FEBIP is suitable for prototyping nanocomponents, in order to solve specific questions and problems in applied nanoelectronics, nanophotonics and nanobiology. Suitable gas molecules are injected close to a sample which is already in the microscope’s vacuum chamber. These adsorb on the sample in a reversible manner. The focussed electron beam, which normally serves to make objects visible, now instead induces chemical reactions of the adsorbed gas molecules, but only at the spot where the beam strikes the surface. The resulting non-volatile molecular fragments then remain permanently on the sample while the volatile fragments are removed by the vacuum system. “With the help of a precisely positioned electron beam, it’s possible to remove or apply with nanometre precision and in virtually any desired three-dimensional shapes,” explains Utke. “FEBIP could soon become a true nanofabrication platform for rapid prototyping of nanostructures in a minimally invasive way, without necessitating the large investment of a clean room.”

Explore further: Engineers' nanoantennas improve infrared sensing

More information: “Polarisation stabilisation of vertical cavity surface emitting lasers by minimally invasive focused electron beam triggered chemistry”, I. Utke, M. Jenke, C. Roeling, P. H. Thiesen, V. Iakovlev, A. Syrbu, A. Mereuta, A. Caliman, E. Kapon, Nanoscale (2011), DOI:10.1039/C1NR10047E

add to favorites email to friend print save as pdf

Related Stories

New VECSEL could mean a step forward for spectroscopy

Oct 25, 2010

(PhysOrg.com) -- "Unfortunately, for spectroscopy, the beam quality of quantum cascade lasers is not satisfying," Hans Zogg tells PhysOrg.com. "We are developing lasers for the mid-infrared range which have an especially good b ...

Better lasers for optical communications

Apr 12, 2011

A new laser procedure could boost optical fiber communications. This technique could become essential for the future expansion of the Internet. It also opens up new frontiers in basic research.

Scientists show atoms act like lasers

Feb 25, 2011

(PhysOrg.com) -- Scientists from The Australian National University have developed an atom laser that behaves exactly like a light laser, opening up new possibilities in things like holograms.

Simpler fabrication of nanogaps

Feb 10, 2011

Plasmons, which are density waves of electrons, are of great interest to pure and applied scientists because of their novel properties, and because of their application to sensing and photonic technologies. ...

Damaging graphene to create a band gap

Nov 22, 2010

(PhysOrg.com) -- "Graphene offers a lot of interesting potential applications for nanoelectronics," Florian Banhart tells PhysOrg.com, "but there is no band gap. This is a well-known problem. Without the band gap, switch ...

Recommended for you

Engineers' nanoantennas improve infrared sensing

30 minutes ago

(Phys.org) —A team of University of Pennsylvania engineers has used a pattern of nanoantennas to develop a new way of turning infrared light into mechanical action, opening the door to more sensitive infrared ...

Stacking 2-D materials produces surprising results

May 16, 2013

(Phys.org) —Graphene has dazzled scientists, ever since its discovery more than a decade ago, with its unequalled electronic properties, its strength and its light weight. But one long-sought goal has proved ...

User comments : 0

More news stories

Engineers' nanoantennas improve infrared sensing

(Phys.org) —A team of University of Pennsylvania engineers has used a pattern of nanoantennas to develop a new way of turning infrared light into mechanical action, opening the door to more sensitive infrared ...

Kinks and curves at the nanoscale

One of the basic principles of nanotechnology is that when you make things extremely small—one nanometer is about five atoms wide, 100,000 times smaller than the diameter of a human hair—they are going ...

Catching graphene butterflies

Writing in Nature, a large international team led Dr Roman Gorbachev from The University of Manchester shows that, when graphene placed on top of insulating boron nitride, or 'white graphene', the electr ...

Mapping a route to stem cell therapies

Monash University researchers are shedding light on the complex processes that underpin the creation and differentiation of stem cells, bringing closer the promise of 'miracle' therapies.

Lymphatic fluid takes detour

When tumours metastasise, they can block lymphatic vessels, as researchers from ETH Zurich have discovered using a new method. The lymphatic fluid subsequently has to find a new path through the tissue. Such ...

Tiny ancient bandicoot shines light on future

(Phys.org) —A 20 million-year-old fossil skull identified as a 'pocket-sized' ancestor of the bandicoot will give insights into the future of Australia's modern endangered animals.