'Green' chemistry extraction method developed for hot capsicum fruit

Jan 18, 2011
This is a graduate student with carotenoids extracted from the dried powder of a red chile cultivar. Also shown are samples of chile powder before (right) and after (left) supercritical fluid extraction. Credit: Photo by Rich Richins

Plant pigments are an important source of non-toxic compounds for use as food or cosmetic coloring agents. In addition to their known nutritional value, the red pigments in Capsicum (chile pepper) are important as sources of non-toxic red dyes; the red pigments are added to many processed foods and cosmetics to enhance their appearance. Certain varieties of Capsicum annuum can be 'extracted' to isolate red-colored xanthophylls, an important economical source of red pigments that can replace carcinogenic synthetic red dyes.

Until now, the common method for extracting red pigments from dried fruit of Capsicum has used hexane as the extraction solvent. A noteworthy new research study from New Mexico State University presents a process for efficient extraction of these red pigments using "". The method recovers 85% or greater of the pigmented carotenoids from dried Capsicum and reduces the hazardous waste and environmental risks associated with traditional extraction methods.

In New Mexico, the economic value of a chile crop includes the value of the fruit harvested as a fresh green product and a dried red product often harvested later in the season. Current extraction processes are limiting; red pigment can only be recovered from American paprika varieties or other mild cultivars. According to a team of researchers from the Department of Plant and Environmental Sciences at New Mexico State University, if extraction of the red pigments could be achieved separate from the capsaicinoids, then a wider range of red-fruited cultivars could be used, including those with important values as fresh green crops.

The scientists created a "green chemical" method that generates an oleoresin from dried Capsicum fruit with virtually the same carotene and xanthophyll composition as the hexane extraction method. The report appears in . Mary A. O'Connell, corresponding author of the study, explained; "If alternative and environmentally sound, "green" extraction protocols could be developed to replace the use of hexane as a solvent for oleoresin production. This would improve the environmental risks for the isolation of red pigments from Capsicum fruit."

The "green" extraction method includes a process that separates the pigments from the capsaicinoids, an important step which the researchers say increases the flexibility of the process to allow a variety of red Capsicum fruit to be used easily for pigment production. The authors noted that this step in the process is critical, as it allows the pigment industry and Capsicum farmers to use virtually any variety of chile regardless of heat level for pigment production. "Pungent chiles with high American Spice Trade Association (ASTA) values could be grown for either food/spice uses or pigment production", they remarked.

The researchers added that since growers may rely on mechanical harvest of chiles in the future, contamination of the red fruit with stems and leaves may become higher with mechanical harvesting than in hand harvesting. They observed that the type of supercritical fluid extraction method presented in this study provides an advantage for red fruit harvests mixed with leaf material because it reduces the amount of chlorophyll that contaminates the carotenoid pigment extracts as compared with a hexane extract.

Explore further: Conjecture on the lateral growth of Type I collagen fibrils

More information: The complete study and abstract are available on the ASHS HortScience electronic journal web site: hortsci.ashspublications.org/c… t/abstract/45/7/1084

Provided by American Society for Horticultural Science

not rated yet
add to favorites email to friend print save as pdf

Related Stories

Red kiwi poised to make a healthy debut

Nov 09, 2005

First there was green, then yellow and now red-fleshed kiwifruit. A team of researchers in Italy and New Zealand has found that a newly developed variety of red-fleshed kiwifruit contain anthocyanins, bright red pigments ...

Feather color is more than skin deep

Apr 15, 2009

Where do birds get their red feathers from? According to Esther del Val, from the National History Museum in Barcelona, Spain, and her team, the red carotenoids that give the common crossbill (Loxia curvirostra) its red coloration ...

Finding the white wine difference

Mar 05, 2007

A CSIRO research team has pinpointed the genetic difference between red (or black) and white grapes – a discovery which could lead to the production of new varieties of grapes and ultimately new wines.

Recommended for you

Chemical biologists find new halogenation enzyme

4 hours ago

Molecules containing carbon-halogen bonds are produced naturally across all kingdoms of life and constitute a large family of natural products with a broad range of biological activities. The presence of halogen substituents ...

Protein secrets of Ebola virus

9 hours ago

The current Ebola virus outbreak in West Africa, which has claimed more than 2000 lives, has highlighted the need for a deeper understanding of the molecular biology of the virus that could be critical in ...

Protein courtship revealed through chemist's lens

9 hours ago

Staying clear of diseases requires that the proteins in our cells cooperate with one another. But, it has been a well-guarded secret how tens of thousands of different proteins find the correct dancing partners ...

Decoding 'sweet codes' that determine protein fates

12 hours ago

We often experience difficulties in identifying the accurate shape of dynamic and fluctuating objects. This is especially the case in the nanoscale world of biomolecules. The research group lead by Professor Koichi Kato of ...

Conjecture on the lateral growth of Type I collagen fibrils

Sep 12, 2014

Whatever the origin and condition of extraction of type I collagen fibrils, in vitro as well as in vivo, the radii of their circular circular cross sections stay distributed in a range going from 50 to 100 nm for the most ...

User comments : 0