(PhysOrg.com) -- Demonstration of precision DNA-based nanoassembly method for making light-emitting particle clusters could lead to advances in solar cells, optoelectronics, and biosensors
By linking individual semiconductor quantum dots with gold nanoparticles, scientists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory have demonstrated the ability to enhance the intensity of light emitted by individual quantum dots by up to 20 times. The precision method for making the light-emitting particle clusters -- published online July 26, 2010 in the journal ChemComm -- will greatly advance scientists’ ability to study and modify the optical properties of quantum dots, and could eventually lead to improved solar energy conversion devices, light-controlled electronics, and biosensors.
“Quantum dots — tiny crystals of semiconductor materials that fluoresce, or emit light, in response to photoexcitation — have enormous potential for use in a wide range of fields from solar energy conversion to computing and medicine,” said Mircea Cotlet, a physical chemist at Brookhaven’s Center for Functional Nanomaterials (CFN) and lead author on the current study. “But many factors can influence the light they emit, and it’s hard to sort out the contributions of these factors in large samples due to the inherent ensemble averaging. Building single-molecule structures at the CFN seemed the ideal way to tease out these effects.”
The Brookhaven team recently developed a precision technique for building such nano-sized structures using short strands of DNA as a highly specific “glue” to link particles together.
“DNA consists of two strands with complementary pairings of bases that stick together in only one way,” explained Oleg Gang, leader of the team that developed the technique. “By varying the length of the individual strands and attaching complementary pieces to the particles we want to join, and anchoring the whole process on an assembly surface, we can precisely control the construction of individual nanoclusters.”
In the current study, the team used this multi-step process to attach semiconductive quantum dots to gold nanoparticles. Metallic materials are known to affect the optical properties of quantum dots, either by enhancing or inhibiting photoluminescence, depending on a range of factors including the size and shape of the materials, the distance between them, and the wavelength of light used to induce photoexcitation.
The precision assembly technique allowed the scientists to control the size, shape, and distance factors to a high degree of precision and test the effect of wavelength in isolation. They specifically chose two wavelengths to test: one close to the so-called “plasmon resonance” of the gold nanoparticles — that is, a wavelength that induces a collective oscillation of the material’s conductive electrons, leading to strong absorption of light at that wavelength — and one outside this range.
The wavelength within the plasmon resonance range enhanced photoluminescence approximately four-fold when compared with the luminescence achieved by the wavelength outside the plasmon resonance range. When compared with the photoluminescence of individual quantum dots not linked to gold nanoparticles, the resonant wavelength enhanced photoluminescence of the gold-linked quantum dots by an order of magnitude.
“This ability to control the excitonic properties in plasmonic fluorescent quantum dots is essential to the development of devices such as solar cells, light emitting diodes, or optical circuits and might improve the sensitivity of quantum-dot based biosensing assays,” Cotlet said.
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