New Finding Opens Path for Designing Novel Complex Oxide Nanomaterials

October 11, 2007
New Finding Opens Path for Designing Novel Complex Oxide Nanomaterials
Atomic orbitals, illustrated above, were once thought to be inactive and play no role in the physical properties of materials. But it turns out that these orbitals do change at the interface of certain types of nanostructures, report physicist Jacques Chakhalian and his colleagues in the journal Science.

A University of Arkansas researcher and his colleagues have found a novel way to "look" at atomic orbitals, and have directly shown for the first time that they change substantially when interacting at the interface of a ferromagnet and a high-temperature superconductor.

This finding opens up a new way of designing nanoscale superconducting materials and fundamentally changes scientific convention, which suggests that only electron spin and atomic charge - not atomic orbitals - influence the properties of superconducting nanostructures. It also has implications for interfaces between other complex oxide materials.

Jacques Chakhalian, assistant professor of physics in the J. William Fulbright College of Arts and Sciences, and his colleagues will publish their findings online at the Science Express Web site, published by the journal Science, on Thursday, Oct. 11.

Until now, materials science researchers believed that an electron's charge and spin influenced the characteristics of conventional bulk materials. Atomic orbitals, which consist of the patterns of electron density that may be formed in an atom, were previously thought to be inactive.

"In conventional materials like copper or silicon, you could account for everything you could see through charge and spin," Chakhalian said. Further, orbitals have proved difficult to "see" through physical experimentation, so it wasn't possible to examine any changes in orbital symmetry that might be taking place at the interface.

Chakhalian's work has focused on what happens at the interface between two different materials - for instance, superconductors and ferromagnets, two materials with properties that were thought to be incompatible with each other in bulk. In 2006, he and his colleagues created the first high-quality material to have both superconducting and ferromagnetic properties, and they used that material in this experiment.

Chakhalian and his colleagues worked with synchrotron radiation at the Advanced Photon Source, Argonne National Laboratory in Argonne, Ill., to examine the interface between a high-temperature superconducting material containing copper oxide and a ferromagnetic material containing manganese oxide. The synchrotron light is electromagnetic radiation of varying wavelengths that can be tuned to a specific wavelength and polarization for a particular experiment. Unlike conventional X-rays, which diffuse through space, the synchrotron light beams are sharply focused, like a laser beam with extreme brilliance.

The researchers forced the two materials into unusual quantum states. Using a technique called resonant X-ray absorption, they were able to "look" at the atomic orbitals at the interface and determine their symmetry in a non-destructive way.

They found that the atomic orbitals changed the nature of their symmetry at the interface and created a covalent bond between the copper and manganese atoms. This bonding does not exist in the bulk of the individual materials

"When you merge these two materials, the atomic orbitals at the interface become important. They start contributing to the electronic properties of the material," Chakhalian said. "This opens a new way of designing materials. We can design quantum materials with engineered physical properties."

The discovery may allow researchers to manipulate nanoscale superconductivity at the interface - opening the possibility of creating room-temperature semiconductors.

Generators that use superconducting materials generate electricity extremely efficiently, at half the size of conventional generators. General Electric estimates the potential market for superconducting generators to be between $20 billion and $30 billion over the next decade.

Source: University of Arkansas

Explore further: Jupiter's moon Europa

Related Stories

Jupiter's moon Europa

September 30, 2015

Jupiter's four largest moons – aka. the Galilean moons, consisting of Io, Europa, Ganymede and Callisto – are nothing if not fascinating. Ever since their discovery over four centuries ago, these moons have been a source ...

'Golden' silver nanoparticle looks and behaves like gold

September 22, 2015

(—In an act of "nano-alchemy," scientists have synthesized a silver (Ag) nanocluster that is virtually identical to a gold (Au) nanocluster. On the outside, the silver nanocluster has a golden yellow color, and ...

The moons of Jupiter

September 15, 2015

Jupiter was appropriately named by the Romans, who chose to name it after the king of the gods. In addition to being the largest planet in our Solar System – with two and a half times the mass of all the other planets combined ...

Recommended for you

Touchless displays superseding touchscreens?

October 2, 2015

While touchscreens are practical, touchless displays would be even more so. That's because, despite touchscreens having enabled the smartphone's advance into our lives and being essential for us to be able to use cash dispensers ...

Physicists map the strain in wonder material graphene

September 29, 2015

This week, an international group of scientists is reporting a breakthrough in the effort to characterize the properties of graphene noninvasively while acquiring information about its response to structural strain.


Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.